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Tetra-μ-acetato-κ(8) O:O′-bis{[N-(4-methylphenyl)pyridin-2-amine-κN (1)]copper(II)}(Cu—Cu)
The complete dinuclear molecule of the title complex, [Cu(2)(CH(3)COO)(4)(C(12)H(12)N(2))(2)], is generated by a centre of inversion. The Cu(II) atoms are connected [Cu—Cu = 2.6329 (16) Å] and bridged by four acetate ligands. The distorted octahedral coordination geometry is completed by a termina...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247553/ https://www.ncbi.nlm.nih.gov/pubmed/22219858 http://dx.doi.org/10.1107/S1600536811044333 |
| _version_ | 1782220133634146304 |
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| author | Fairuz, Zainal Abidin Aiyub, Zaharah Abdullah, Zanariah Ng, Seik Weng Tiekink, Edward R. T. |
| author_facet | Fairuz, Zainal Abidin Aiyub, Zaharah Abdullah, Zanariah Ng, Seik Weng Tiekink, Edward R. T. |
| author_sort | Fairuz, Zainal Abidin |
| collection | PubMed |
| description | The complete dinuclear molecule of the title complex, [Cu(2)(CH(3)COO)(4)(C(12)H(12)N(2))(2)], is generated by a centre of inversion. The Cu(II) atoms are connected [Cu—Cu = 2.6329 (16) Å] and bridged by four acetate ligands. The distorted octahedral coordination geometry is completed by a terminal pyridine N atom. The amine H atom forms an intramolecular N—H⋯O hydrogen bond. |
| format | Online Article Text |
| id | pubmed-3247553 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32475532012-01-04 Tetra-μ-acetato-κ(8) O:O′-bis{[N-(4-methylphenyl)pyridin-2-amine-κN (1)]copper(II)}(Cu—Cu) Fairuz, Zainal Abidin Aiyub, Zaharah Abdullah, Zanariah Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete dinuclear molecule of the title complex, [Cu(2)(CH(3)COO)(4)(C(12)H(12)N(2))(2)], is generated by a centre of inversion. The Cu(II) atoms are connected [Cu—Cu = 2.6329 (16) Å] and bridged by four acetate ligands. The distorted octahedral coordination geometry is completed by a terminal pyridine N atom. The amine H atom forms an intramolecular N—H⋯O hydrogen bond. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247553/ /pubmed/22219858 http://dx.doi.org/10.1107/S1600536811044333 Text en © Fairuz et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Fairuz, Zainal Abidin Aiyub, Zaharah Abdullah, Zanariah Ng, Seik Weng Tiekink, Edward R. T. Tetra-μ-acetato-κ(8) O:O′-bis{[N-(4-methylphenyl)pyridin-2-amine-κN (1)]copper(II)}(Cu—Cu) |
| title | Tetra-μ-acetato-κ(8)
O:O′-bis{[N-(4-methylphenyl)pyridin-2-amine-κN
(1)]copper(II)}(Cu—Cu) |
| title_full | Tetra-μ-acetato-κ(8)
O:O′-bis{[N-(4-methylphenyl)pyridin-2-amine-κN
(1)]copper(II)}(Cu—Cu) |
| title_fullStr | Tetra-μ-acetato-κ(8)
O:O′-bis{[N-(4-methylphenyl)pyridin-2-amine-κN
(1)]copper(II)}(Cu—Cu) |
| title_full_unstemmed | Tetra-μ-acetato-κ(8)
O:O′-bis{[N-(4-methylphenyl)pyridin-2-amine-κN
(1)]copper(II)}(Cu—Cu) |
| title_short | Tetra-μ-acetato-κ(8)
O:O′-bis{[N-(4-methylphenyl)pyridin-2-amine-κN
(1)]copper(II)}(Cu—Cu) |
| title_sort | tetra-μ-acetato-κ(8)
o:o′-bis{[n-(4-methylphenyl)pyridin-2-amine-κn
(1)]copper(ii)}(cu—cu) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247553/ https://www.ncbi.nlm.nih.gov/pubmed/22219858 http://dx.doi.org/10.1107/S1600536811044333 |
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