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trans-Diaquabis(4-fluorobenzoato-κO)bis(nicotinamide-κN (1))nickel(II)
In the mononuclear Ni(II) title complex, [Ni(C(7)H(4)FO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Ni(II) atom, located on an inversion center, is coordinated by two nicotinamide and two 4-fluorobenzoate ligands and two water molecules in a distorted N(2)O(4) octahedral geometry. The dihedral angle...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247555/ https://www.ncbi.nlm.nih.gov/pubmed/22219860 http://dx.doi.org/10.1107/S1600536811044771 |
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author | Necefoğlu, Hacali Öztürk, Vijdan Özbek, Füreya Elif Adıgüzel, Vedat Hökelek, Tuncer |
author_facet | Necefoğlu, Hacali Öztürk, Vijdan Özbek, Füreya Elif Adıgüzel, Vedat Hökelek, Tuncer |
author_sort | Necefoğlu, Hacali |
collection | PubMed |
description | In the mononuclear Ni(II) title complex, [Ni(C(7)H(4)FO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Ni(II) atom, located on an inversion center, is coordinated by two nicotinamide and two 4-fluorobenzoate ligands and two water molecules in a distorted N(2)O(4) octahedral geometry. The dihedral angle between the carboxylate group and the adjacent benzene ring is 8.95 (8)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 75.01 (7)°. The water molecule links the adjacent carboxylate O atom via an intramolecular O—H⋯O hydrogen bond. In the crystal, O—H⋯O, N—H⋯O, C—H⋯O and C—H⋯F hydrogen bonds link the molecules into a three-dimensional network. π–π stacking between parallel pyridine rings [centroid–centroid distance = 3.7287 (11) Å] is also observed. |
format | Online Article Text |
id | pubmed-3247555 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32475552012-01-04 trans-Diaquabis(4-fluorobenzoato-κO)bis(nicotinamide-κN (1))nickel(II) Necefoğlu, Hacali Öztürk, Vijdan Özbek, Füreya Elif Adıgüzel, Vedat Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear Ni(II) title complex, [Ni(C(7)H(4)FO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Ni(II) atom, located on an inversion center, is coordinated by two nicotinamide and two 4-fluorobenzoate ligands and two water molecules in a distorted N(2)O(4) octahedral geometry. The dihedral angle between the carboxylate group and the adjacent benzene ring is 8.95 (8)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 75.01 (7)°. The water molecule links the adjacent carboxylate O atom via an intramolecular O—H⋯O hydrogen bond. In the crystal, O—H⋯O, N—H⋯O, C—H⋯O and C—H⋯F hydrogen bonds link the molecules into a three-dimensional network. π–π stacking between parallel pyridine rings [centroid–centroid distance = 3.7287 (11) Å] is also observed. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247555/ /pubmed/22219860 http://dx.doi.org/10.1107/S1600536811044771 Text en © Necefoğlu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Necefoğlu, Hacali Öztürk, Vijdan Özbek, Füreya Elif Adıgüzel, Vedat Hökelek, Tuncer trans-Diaquabis(4-fluorobenzoato-κO)bis(nicotinamide-κN (1))nickel(II) |
title |
trans-Diaquabis(4-fluorobenzoato-κO)bis(nicotinamide-κN
(1))nickel(II) |
title_full |
trans-Diaquabis(4-fluorobenzoato-κO)bis(nicotinamide-κN
(1))nickel(II) |
title_fullStr |
trans-Diaquabis(4-fluorobenzoato-κO)bis(nicotinamide-κN
(1))nickel(II) |
title_full_unstemmed |
trans-Diaquabis(4-fluorobenzoato-κO)bis(nicotinamide-κN
(1))nickel(II) |
title_short |
trans-Diaquabis(4-fluorobenzoato-κO)bis(nicotinamide-κN
(1))nickel(II) |
title_sort | trans-diaquabis(4-fluorobenzoato-κo)bis(nicotinamide-κn
(1))nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247555/ https://www.ncbi.nlm.nih.gov/pubmed/22219860 http://dx.doi.org/10.1107/S1600536811044771 |
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