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trans-Diaqua­bis­(4-fluoro­benzoato-κO)bis­(nicotinamide-κN (1))nickel(II)

In the mononuclear Ni(II) title complex, [Ni(C(7)H(4)FO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Ni(II) atom, located on an inversion center, is coordinated by two nicotinamide and two 4-fluoro­benzoate ligands and two water mol­ecules in a distorted N(2)O(4) octa­hedral geometry. The dihedral angle...

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Autores principales: Necefoğlu, Hacali, Öztürk, Vijdan, Özbek, Füreya Elif, Adıgüzel, Vedat, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247555/
https://www.ncbi.nlm.nih.gov/pubmed/22219860
http://dx.doi.org/10.1107/S1600536811044771
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author Necefoğlu, Hacali
Öztürk, Vijdan
Özbek, Füreya Elif
Adıgüzel, Vedat
Hökelek, Tuncer
author_facet Necefoğlu, Hacali
Öztürk, Vijdan
Özbek, Füreya Elif
Adıgüzel, Vedat
Hökelek, Tuncer
author_sort Necefoğlu, Hacali
collection PubMed
description In the mononuclear Ni(II) title complex, [Ni(C(7)H(4)FO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Ni(II) atom, located on an inversion center, is coordinated by two nicotinamide and two 4-fluoro­benzoate ligands and two water mol­ecules in a distorted N(2)O(4) octa­hedral geometry. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 8.95 (8)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 75.01 (7)°. The water mol­ecule links the adjacent carboxyl­ate O atom via an intra­molecular O—H⋯O hydrogen bond. In the crystal, O—H⋯O, N—H⋯O, C—H⋯O and C—H⋯F hydrogen bonds link the mol­ecules into a three-dimensional network. π–π stacking between parallel pyridine rings [centroid–centroid distance = 3.7287 (11) Å] is also observed.
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spelling pubmed-32475552012-01-04 trans-Diaqua­bis­(4-fluoro­benzoato-κO)bis­(nicotinamide-κN (1))nickel(II) Necefoğlu, Hacali Öztürk, Vijdan Özbek, Füreya Elif Adıgüzel, Vedat Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear Ni(II) title complex, [Ni(C(7)H(4)FO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], the Ni(II) atom, located on an inversion center, is coordinated by two nicotinamide and two 4-fluoro­benzoate ligands and two water mol­ecules in a distorted N(2)O(4) octa­hedral geometry. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 8.95 (8)°, while the pyridine ring and the benzene ring are oriented at a dihedral angle of 75.01 (7)°. The water mol­ecule links the adjacent carboxyl­ate O atom via an intra­molecular O—H⋯O hydrogen bond. In the crystal, O—H⋯O, N—H⋯O, C—H⋯O and C—H⋯F hydrogen bonds link the mol­ecules into a three-dimensional network. π–π stacking between parallel pyridine rings [centroid–centroid distance = 3.7287 (11) Å] is also observed. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247555/ /pubmed/22219860 http://dx.doi.org/10.1107/S1600536811044771 Text en © Necefoğlu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Necefoğlu, Hacali
Öztürk, Vijdan
Özbek, Füreya Elif
Adıgüzel, Vedat
Hökelek, Tuncer
trans-Diaqua­bis­(4-fluoro­benzoato-κO)bis­(nicotinamide-κN (1))nickel(II)
title trans-Diaqua­bis­(4-fluoro­benzoato-κO)bis­(nicotinamide-κN (1))nickel(II)
title_full trans-Diaqua­bis­(4-fluoro­benzoato-κO)bis­(nicotinamide-κN (1))nickel(II)
title_fullStr trans-Diaqua­bis­(4-fluoro­benzoato-κO)bis­(nicotinamide-κN (1))nickel(II)
title_full_unstemmed trans-Diaqua­bis­(4-fluoro­benzoato-κO)bis­(nicotinamide-κN (1))nickel(II)
title_short trans-Diaqua­bis­(4-fluoro­benzoato-κO)bis­(nicotinamide-κN (1))nickel(II)
title_sort trans-diaqua­bis­(4-fluoro­benzoato-κo)bis­(nicotinamide-κn (1))nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247555/
https://www.ncbi.nlm.nih.gov/pubmed/22219860
http://dx.doi.org/10.1107/S1600536811044771
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