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Poly[tetra-n-butylammonium [(μ(5)-benzene-1,3,5-tricarboxylato)(μ(4)-benzene-1,3,5-tricarboxylato)-μ(3)-hydroxido-trizincate] 0.25-hydrate]
In the asymmetric unit of title coordination polymer, {(C(16)H(36)N)[Zn(3)(C(9)H(3)O(6))(2)(OH)]·0.25H(2)O}(n), there are three independent Zn(2+) cations, two benzene-1,3,5-tricarboxylate ligands and a μ(3)-bridging hydroxide group, together with a tetra-n-butylammonium counter-cation and a parti...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247557/ https://www.ncbi.nlm.nih.gov/pubmed/22219862 http://dx.doi.org/10.1107/S1600536811044485 |
Sumario: | In the asymmetric unit of title coordination polymer, {(C(16)H(36)N)[Zn(3)(C(9)H(3)O(6))(2)(OH)]·0.25H(2)O}(n), there are three independent Zn(2+) cations, two benzene-1,3,5-tricarboxylate ligands and a μ(3)-bridging hydroxide group, together with a tetra-n-butylammonium counter-cation and a partially occupied water molecule of solvation (occupancy 0.25). Each Zn ion is coordinated by three carboxylate O atoms and one O atom from the bridging hydroxide ion, displaying a slightly distorted tetrahedral stereochemistry [overall Zn—O range = 1.875 (3)–1.987 (2) Å]. An intramolecular hydrogen bond involving the hydroxide H atom and a carboxylate O-atom acceptor is also present in the complex unit. The bridging benzene-1,3,5-tricarboxylate anions generate a three-dimensional framework structure. |
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