Cargando…
Poly[tetra-n-butylammonium [(μ(5)-benzene-1,3,5-tricarboxylato)(μ(4)-benzene-1,3,5-tricarboxylato)-μ(3)-hydroxido-trizincate] 0.25-hydrate]
In the asymmetric unit of title coordination polymer, {(C(16)H(36)N)[Zn(3)(C(9)H(3)O(6))(2)(OH)]·0.25H(2)O}(n), there are three independent Zn(2+) cations, two benzene-1,3,5-tricarboxylate ligands and a μ(3)-bridging hydroxide group, together with a tetra-n-butylammonium counter-cation and a parti...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247557/ https://www.ncbi.nlm.nih.gov/pubmed/22219862 http://dx.doi.org/10.1107/S1600536811044485 |
_version_ | 1782220134555844608 |
---|---|
author | Zhu, Xiao-Hong Cheng, Xiao-Chun |
author_facet | Zhu, Xiao-Hong Cheng, Xiao-Chun |
author_sort | Zhu, Xiao-Hong |
collection | PubMed |
description | In the asymmetric unit of title coordination polymer, {(C(16)H(36)N)[Zn(3)(C(9)H(3)O(6))(2)(OH)]·0.25H(2)O}(n), there are three independent Zn(2+) cations, two benzene-1,3,5-tricarboxylate ligands and a μ(3)-bridging hydroxide group, together with a tetra-n-butylammonium counter-cation and a partially occupied water molecule of solvation (occupancy 0.25). Each Zn ion is coordinated by three carboxylate O atoms and one O atom from the bridging hydroxide ion, displaying a slightly distorted tetrahedral stereochemistry [overall Zn—O range = 1.875 (3)–1.987 (2) Å]. An intramolecular hydrogen bond involving the hydroxide H atom and a carboxylate O-atom acceptor is also present in the complex unit. The bridging benzene-1,3,5-tricarboxylate anions generate a three-dimensional framework structure. |
format | Online Article Text |
id | pubmed-3247557 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32475572012-01-04 Poly[tetra-n-butylammonium [(μ(5)-benzene-1,3,5-tricarboxylato)(μ(4)-benzene-1,3,5-tricarboxylato)-μ(3)-hydroxido-trizincate] 0.25-hydrate] Zhu, Xiao-Hong Cheng, Xiao-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the asymmetric unit of title coordination polymer, {(C(16)H(36)N)[Zn(3)(C(9)H(3)O(6))(2)(OH)]·0.25H(2)O}(n), there are three independent Zn(2+) cations, two benzene-1,3,5-tricarboxylate ligands and a μ(3)-bridging hydroxide group, together with a tetra-n-butylammonium counter-cation and a partially occupied water molecule of solvation (occupancy 0.25). Each Zn ion is coordinated by three carboxylate O atoms and one O atom from the bridging hydroxide ion, displaying a slightly distorted tetrahedral stereochemistry [overall Zn—O range = 1.875 (3)–1.987 (2) Å]. An intramolecular hydrogen bond involving the hydroxide H atom and a carboxylate O-atom acceptor is also present in the complex unit. The bridging benzene-1,3,5-tricarboxylate anions generate a three-dimensional framework structure. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247557/ /pubmed/22219862 http://dx.doi.org/10.1107/S1600536811044485 Text en © Zhu and Cheng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhu, Xiao-Hong Cheng, Xiao-Chun Poly[tetra-n-butylammonium [(μ(5)-benzene-1,3,5-tricarboxylato)(μ(4)-benzene-1,3,5-tricarboxylato)-μ(3)-hydroxido-trizincate] 0.25-hydrate] |
title | Poly[tetra-n-butylammonium [(μ(5)-benzene-1,3,5-tricarboxylato)(μ(4)-benzene-1,3,5-tricarboxylato)-μ(3)-hydroxido-trizincate] 0.25-hydrate] |
title_full | Poly[tetra-n-butylammonium [(μ(5)-benzene-1,3,5-tricarboxylato)(μ(4)-benzene-1,3,5-tricarboxylato)-μ(3)-hydroxido-trizincate] 0.25-hydrate] |
title_fullStr | Poly[tetra-n-butylammonium [(μ(5)-benzene-1,3,5-tricarboxylato)(μ(4)-benzene-1,3,5-tricarboxylato)-μ(3)-hydroxido-trizincate] 0.25-hydrate] |
title_full_unstemmed | Poly[tetra-n-butylammonium [(μ(5)-benzene-1,3,5-tricarboxylato)(μ(4)-benzene-1,3,5-tricarboxylato)-μ(3)-hydroxido-trizincate] 0.25-hydrate] |
title_short | Poly[tetra-n-butylammonium [(μ(5)-benzene-1,3,5-tricarboxylato)(μ(4)-benzene-1,3,5-tricarboxylato)-μ(3)-hydroxido-trizincate] 0.25-hydrate] |
title_sort | poly[tetra-n-butylammonium [(μ(5)-benzene-1,3,5-tricarboxylato)(μ(4)-benzene-1,3,5-tricarboxylato)-μ(3)-hydroxido-trizincate] 0.25-hydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247557/ https://www.ncbi.nlm.nih.gov/pubmed/22219862 http://dx.doi.org/10.1107/S1600536811044485 |
work_keys_str_mv | AT zhuxiaohong polytetranbutylammoniumm5benzene135tricarboxylatom4benzene135tricarboxylatom3hydroxidotrizincate025hydrate AT chengxiaochun polytetranbutylammoniumm5benzene135tricarboxylatom4benzene135tricarboxylatom3hydroxidotrizincate025hydrate |