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Poly[tetra-n-butyl­ammonium [(μ(5)-benzene-1,3,5-tricarboxyl­ato)(μ(4)-benzene-1,3,5-tricarboxyl­ato)-μ(3)-hydroxido-trizincate] 0.25-hydrate]

In the asymmetric unit of title coordination polymer, {(C(16)H(36)N)[Zn(3)(C(9)H(3)O(6))(2)(OH)]·0.25H(2)O}(n), there are three independent Zn(2+) cations, two benzene-1,3,5-tricarboxyl­ate ligands and a μ(3)-bridging hydroxide group, together with a tetra-n-butyl­ammonium counter-cation and a parti...

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Detalles Bibliográficos
Autores principales: Zhu, Xiao-Hong, Cheng, Xiao-Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247557/
https://www.ncbi.nlm.nih.gov/pubmed/22219862
http://dx.doi.org/10.1107/S1600536811044485
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author Zhu, Xiao-Hong
Cheng, Xiao-Chun
author_facet Zhu, Xiao-Hong
Cheng, Xiao-Chun
author_sort Zhu, Xiao-Hong
collection PubMed
description In the asymmetric unit of title coordination polymer, {(C(16)H(36)N)[Zn(3)(C(9)H(3)O(6))(2)(OH)]·0.25H(2)O}(n), there are three independent Zn(2+) cations, two benzene-1,3,5-tricarboxyl­ate ligands and a μ(3)-bridging hydroxide group, together with a tetra-n-butyl­ammonium counter-cation and a partially occupied water molecule of solvation (occupancy 0.25). Each Zn ion is coordinated by three carboxyl­ate O atoms and one O atom from the bridging hydroxide ion, displaying a slightly distorted tetra­hedral stereochemistry [overall Zn—O range = 1.875 (3)–1.987 (2) Å]. An intra­molecular hydrogen bond involving the hydroxide H atom and a carboxyl­ate O-atom acceptor is also present in the complex unit. The bridging benzene-1,3,5-tricarboxyl­ate anions generate a three-dimensional framework structure.
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spelling pubmed-32475572012-01-04 Poly[tetra-n-butyl­ammonium [(μ(5)-benzene-1,3,5-tricarboxyl­ato)(μ(4)-benzene-1,3,5-tricarboxyl­ato)-μ(3)-hydroxido-trizincate] 0.25-hydrate] Zhu, Xiao-Hong Cheng, Xiao-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the asymmetric unit of title coordination polymer, {(C(16)H(36)N)[Zn(3)(C(9)H(3)O(6))(2)(OH)]·0.25H(2)O}(n), there are three independent Zn(2+) cations, two benzene-1,3,5-tricarboxyl­ate ligands and a μ(3)-bridging hydroxide group, together with a tetra-n-butyl­ammonium counter-cation and a partially occupied water molecule of solvation (occupancy 0.25). Each Zn ion is coordinated by three carboxyl­ate O atoms and one O atom from the bridging hydroxide ion, displaying a slightly distorted tetra­hedral stereochemistry [overall Zn—O range = 1.875 (3)–1.987 (2) Å]. An intra­molecular hydrogen bond involving the hydroxide H atom and a carboxyl­ate O-atom acceptor is also present in the complex unit. The bridging benzene-1,3,5-tricarboxyl­ate anions generate a three-dimensional framework structure. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3247557/ /pubmed/22219862 http://dx.doi.org/10.1107/S1600536811044485 Text en © Zhu and Cheng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Xiao-Hong
Cheng, Xiao-Chun
Poly[tetra-n-butyl­ammonium [(μ(5)-benzene-1,3,5-tricarboxyl­ato)(μ(4)-benzene-1,3,5-tricarboxyl­ato)-μ(3)-hydroxido-trizincate] 0.25-hydrate]
title Poly[tetra-n-butyl­ammonium [(μ(5)-benzene-1,3,5-tricarboxyl­ato)(μ(4)-benzene-1,3,5-tricarboxyl­ato)-μ(3)-hydroxido-trizincate] 0.25-hydrate]
title_full Poly[tetra-n-butyl­ammonium [(μ(5)-benzene-1,3,5-tricarboxyl­ato)(μ(4)-benzene-1,3,5-tricarboxyl­ato)-μ(3)-hydroxido-trizincate] 0.25-hydrate]
title_fullStr Poly[tetra-n-butyl­ammonium [(μ(5)-benzene-1,3,5-tricarboxyl­ato)(μ(4)-benzene-1,3,5-tricarboxyl­ato)-μ(3)-hydroxido-trizincate] 0.25-hydrate]
title_full_unstemmed Poly[tetra-n-butyl­ammonium [(μ(5)-benzene-1,3,5-tricarboxyl­ato)(μ(4)-benzene-1,3,5-tricarboxyl­ato)-μ(3)-hydroxido-trizincate] 0.25-hydrate]
title_short Poly[tetra-n-butyl­ammonium [(μ(5)-benzene-1,3,5-tricarboxyl­ato)(μ(4)-benzene-1,3,5-tricarboxyl­ato)-μ(3)-hydroxido-trizincate] 0.25-hydrate]
title_sort poly[tetra-n-butyl­ammonium [(μ(5)-benzene-1,3,5-tricarboxyl­ato)(μ(4)-benzene-1,3,5-tricarboxyl­ato)-μ(3)-hydroxido-trizincate] 0.25-hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247557/
https://www.ncbi.nlm.nih.gov/pubmed/22219862
http://dx.doi.org/10.1107/S1600536811044485
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AT chengxiaochun polytetranbutylammoniumm5benzene135tricarboxylatom4benzene135tricarboxylatom3hydroxidotrizincate025hydrate