2-Trifluoro­methyl-1H-benzimidazol-3-ium perchlorate

In the title salt, C(8)H(6)F(3)N(2) (+)·ClO(4) (−), the atoms of the benzimidazole ring (including H atoms) are nearly coplanar (r.m.s. deviation of the fitted atoms = 0.0122 Å) and the triflouromethyl group lies out of this plane. The perchlorate anion adopts a distorted tetra­hedral conformation w...

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Autor principal: Liu, Ming-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247562/
https://www.ncbi.nlm.nih.gov/pubmed/22219867
http://dx.doi.org/10.1107/S1600536811039298
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author Liu, Ming-Liang
author_facet Liu, Ming-Liang
author_sort Liu, Ming-Liang
collection PubMed
description In the title salt, C(8)H(6)F(3)N(2) (+)·ClO(4) (−), the atoms of the benzimidazole ring (including H atoms) are nearly coplanar (r.m.s. deviation of the fitted atoms = 0.0122 Å) and the triflouromethyl group lies out of this plane. The perchlorate anion adopts a distorted tetra­hedral conformation with the Cl—O bond distances ranging from 1.412 (3) to 1.439 (2) Å. The benzimidazolium cations are linked to adjacent anions by inter­molecular N—H⋯O hydrogen bonds, forming chains.
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spelling pubmed-32475622012-01-04 2-Trifluoro­methyl-1H-benzimidazol-3-ium perchlorate Liu, Ming-Liang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(8)H(6)F(3)N(2) (+)·ClO(4) (−), the atoms of the benzimidazole ring (including H atoms) are nearly coplanar (r.m.s. deviation of the fitted atoms = 0.0122 Å) and the triflouromethyl group lies out of this plane. The perchlorate anion adopts a distorted tetra­hedral conformation with the Cl—O bond distances ranging from 1.412 (3) to 1.439 (2) Å. The benzimidazolium cations are linked to adjacent anions by inter­molecular N—H⋯O hydrogen bonds, forming chains. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3247562/ /pubmed/22219867 http://dx.doi.org/10.1107/S1600536811039298 Text en © Ming-Liang Liu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Ming-Liang
2-Trifluoro­methyl-1H-benzimidazol-3-ium perchlorate
title 2-Trifluoro­methyl-1H-benzimidazol-3-ium perchlorate
title_full 2-Trifluoro­methyl-1H-benzimidazol-3-ium perchlorate
title_fullStr 2-Trifluoro­methyl-1H-benzimidazol-3-ium perchlorate
title_full_unstemmed 2-Trifluoro­methyl-1H-benzimidazol-3-ium perchlorate
title_short 2-Trifluoro­methyl-1H-benzimidazol-3-ium perchlorate
title_sort 2-trifluoro­methyl-1h-benzimidazol-3-ium perchlorate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247562/
https://www.ncbi.nlm.nih.gov/pubmed/22219867
http://dx.doi.org/10.1107/S1600536811039298
work_keys_str_mv AT liumingliang 2trifluoromethyl1hbenzimidazol3iumperchlorate

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