4-Chloro-N′-(2-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate

The title compound, C(15)H(13)ClN(2)O(3)·CH(3)OH, was synthesized by the condensation reaction of 2-hy­droxy-4-meth­oxy­benzaldehyde with 4-chloro­benzohydrazide in methanol. The Schiff base mol­ecule displays a trans configuration with respect to the C=N and C—N bonds. The dihedral angle between th...

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Detalles Bibliográficos
Autores principales: Zhi, Feng, Wang, Rong, Zhang, Yi, Wang, Qiang, Yang, Yi-Lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247565/
https://www.ncbi.nlm.nih.gov/pubmed/22219870
http://dx.doi.org/10.1107/S1600536811039778
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author Zhi, Feng
Wang, Rong
Zhang, Yi
Wang, Qiang
Yang, Yi-Lin
author_facet Zhi, Feng
Wang, Rong
Zhang, Yi
Wang, Qiang
Yang, Yi-Lin
author_sort Zhi, Feng
collection PubMed
description The title compound, C(15)H(13)ClN(2)O(3)·CH(3)OH, was synthesized by the condensation reaction of 2-hy­droxy-4-meth­oxy­benzaldehyde with 4-chloro­benzohydrazide in methanol. The Schiff base mol­ecule displays a trans configuration with respect to the C=N and C—N bonds. The dihedral angle between the two benzene rings is 5.3 (2)°. In the crystal, mol­ecules are linked by N—H⋯O and O—H⋯O hydrogen-bond inter­actions into chains running parallel to the a axis. An intra­molecular O—H⋯N hydrogen bond is observed.
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spelling pubmed-32475652012-01-04 4-Chloro-N′-(2-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate Zhi, Feng Wang, Rong Zhang, Yi Wang, Qiang Yang, Yi-Lin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(13)ClN(2)O(3)·CH(3)OH, was synthesized by the condensation reaction of 2-hy­droxy-4-meth­oxy­benzaldehyde with 4-chloro­benzohydrazide in methanol. The Schiff base mol­ecule displays a trans configuration with respect to the C=N and C—N bonds. The dihedral angle between the two benzene rings is 5.3 (2)°. In the crystal, mol­ecules are linked by N—H⋯O and O—H⋯O hydrogen-bond inter­actions into chains running parallel to the a axis. An intra­molecular O—H⋯N hydrogen bond is observed. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3247565/ /pubmed/22219870 http://dx.doi.org/10.1107/S1600536811039778 Text en © Zhi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhi, Feng
Wang, Rong
Zhang, Yi
Wang, Qiang
Yang, Yi-Lin
4-Chloro-N′-(2-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate
title 4-Chloro-N′-(2-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate
title_full 4-Chloro-N′-(2-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate
title_fullStr 4-Chloro-N′-(2-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate
title_full_unstemmed 4-Chloro-N′-(2-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate
title_short 4-Chloro-N′-(2-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate
title_sort 4-chloro-n′-(2-hy­droxy-4-meth­oxy­benzyl­idene)benzohydrazide methanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247565/
https://www.ncbi.nlm.nih.gov/pubmed/22219870
http://dx.doi.org/10.1107/S1600536811039778
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