2-(2-Bromo­eth­yl)isoindoline-1,3-dione

The asymmetric unit of the title compound, C(10)H(8)BrNO(2), contains three crystallographically independent mol­ecules. Two of the N—C—C—Br side chains adopt anti conformations [torsion angles = −179.8 (5) and −179.4 (4)°] and the other is gauche [−66.5 (6)°]. The crystal structure features short B...

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Detalles Bibliográficos
Autores principales: Sun, Xiao-Qiang, An, Dong, Shao, Ying
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247571/
https://www.ncbi.nlm.nih.gov/pubmed/22219876
http://dx.doi.org/10.1107/S1600536811039808
Descripción
Sumario:The asymmetric unit of the title compound, C(10)H(8)BrNO(2), contains three crystallographically independent mol­ecules. Two of the N—C—C—Br side chains adopt anti conformations [torsion angles = −179.8 (5) and −179.4 (4)°] and the other is gauche [−66.5 (6)°]. The crystal structure features short Br⋯O [3.162 (5) Å] contacts, C—H⋯O hydrogen bonds and numerous π–π stacking inter­actions [centroid–centroid separations = 3.517 (4)–3.950 (4) Å].

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