8-{[(E)-3-(2-Chloro­phen­yl)acrylo­yloxy]imino}-12,13-ep­oxy­trichethec-9-en-4-yl (E)-3-(2-chloro­phen­yl)acrylate

In the title compound, C(33)H(31)Cl(2)NO(6), the five-membered ring displays an envelope conformation, whereas the two six-membered rings both exhibit a chair conformation. As for the seven-membered ring, the dihedral angle between the mean planes formed by the four C atoms of the envelope unit and...

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Detalles Bibliográficos
Autores principales: Xu, Xiao-Jun, Li, Xiao-Liang, Cheng, Jing-li, Zhao, Jin-hao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247573/
https://www.ncbi.nlm.nih.gov/pubmed/22219878
http://dx.doi.org/10.1107/S1600536811039638
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author Xu, Xiao-Jun
Li, Xiao-Liang
Cheng, Jing-li
Zhao, Jin-hao
author_facet Xu, Xiao-Jun
Li, Xiao-Liang
Cheng, Jing-li
Zhao, Jin-hao
author_sort Xu, Xiao-Jun
collection PubMed
description In the title compound, C(33)H(31)Cl(2)NO(6), the five-membered ring displays an envelope conformation, whereas the two six-membered rings both exhibit a chair conformation. As for the seven-membered ring, the dihedral angle between the mean planes formed by the four C atoms of the envelope unit and the three C and one O atoms of the six-membered chair is 69.08 (4)°, and these two mean planes are nearly perpendicular to the ep­oxy ring, making dihedral angles of 87.53 (4) and 88.67 (4)°, respectively.
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spelling pubmed-32475732012-01-04 8-{[(E)-3-(2-Chloro­phen­yl)acrylo­yloxy]imino}-12,13-ep­oxy­trichethec-9-en-4-yl (E)-3-(2-chloro­phen­yl)acrylate Xu, Xiao-Jun Li, Xiao-Liang Cheng, Jing-li Zhao, Jin-hao Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(33)H(31)Cl(2)NO(6), the five-membered ring displays an envelope conformation, whereas the two six-membered rings both exhibit a chair conformation. As for the seven-membered ring, the dihedral angle between the mean planes formed by the four C atoms of the envelope unit and the three C and one O atoms of the six-membered chair is 69.08 (4)°, and these two mean planes are nearly perpendicular to the ep­oxy ring, making dihedral angles of 87.53 (4) and 88.67 (4)°, respectively. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3247573/ /pubmed/22219878 http://dx.doi.org/10.1107/S1600536811039638 Text en © Xu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xu, Xiao-Jun
Li, Xiao-Liang
Cheng, Jing-li
Zhao, Jin-hao
8-{[(E)-3-(2-Chloro­phen­yl)acrylo­yloxy]imino}-12,13-ep­oxy­trichethec-9-en-4-yl (E)-3-(2-chloro­phen­yl)acrylate
title 8-{[(E)-3-(2-Chloro­phen­yl)acrylo­yloxy]imino}-12,13-ep­oxy­trichethec-9-en-4-yl (E)-3-(2-chloro­phen­yl)acrylate
title_full 8-{[(E)-3-(2-Chloro­phen­yl)acrylo­yloxy]imino}-12,13-ep­oxy­trichethec-9-en-4-yl (E)-3-(2-chloro­phen­yl)acrylate
title_fullStr 8-{[(E)-3-(2-Chloro­phen­yl)acrylo­yloxy]imino}-12,13-ep­oxy­trichethec-9-en-4-yl (E)-3-(2-chloro­phen­yl)acrylate
title_full_unstemmed 8-{[(E)-3-(2-Chloro­phen­yl)acrylo­yloxy]imino}-12,13-ep­oxy­trichethec-9-en-4-yl (E)-3-(2-chloro­phen­yl)acrylate
title_short 8-{[(E)-3-(2-Chloro­phen­yl)acrylo­yloxy]imino}-12,13-ep­oxy­trichethec-9-en-4-yl (E)-3-(2-chloro­phen­yl)acrylate
title_sort 8-{[(e)-3-(2-chloro­phen­yl)acrylo­yloxy]imino}-12,13-ep­oxy­trichethec-9-en-4-yl (e)-3-(2-chloro­phen­yl)acrylate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247573/
https://www.ncbi.nlm.nih.gov/pubmed/22219878
http://dx.doi.org/10.1107/S1600536811039638
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AT chengjingli 8e32chlorophenylacryloyloxyimino1213epoxytrichethec9en4yle32chlorophenylacrylate
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