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N′-(4-Fluoro­benzyl­idene)-2-(4-fluoro­phen­yl)acetohydrazide

In the title compound, C(15)H(12)F(2)N(2)O, the dihedral angle between the two benzene rings is 48.73 (8)°. The hydrazine group is twisted slightly, with a C—N—N—C torsion angle of 172.48 (12)°. In the crystal, mol­ecules are connected by strong N—H⋯O and weak C—H⋯O hydrogen bonds, forming supra­mol...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Hemamalini, Madhukar, Sumangala, V., Nagaraja, G. K., Poojary, Boja
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247574/
https://www.ncbi.nlm.nih.gov/pubmed/22219879
http://dx.doi.org/10.1107/S1600536811039845
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author Fun, Hoong-Kun
Hemamalini, Madhukar
Sumangala, V.
Nagaraja, G. K.
Poojary, Boja
author_facet Fun, Hoong-Kun
Hemamalini, Madhukar
Sumangala, V.
Nagaraja, G. K.
Poojary, Boja
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(15)H(12)F(2)N(2)O, the dihedral angle between the two benzene rings is 48.73 (8)°. The hydrazine group is twisted slightly, with a C—N—N—C torsion angle of 172.48 (12)°. In the crystal, mol­ecules are connected by strong N—H⋯O and weak C—H⋯O hydrogen bonds, forming supra­molecular chains along the c axis. The structure is consolidated by π–π [centroid–centroid separation = 3.6579 (10) Å] and C—H⋯π inter­actions.
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spelling pubmed-32475742012-01-04 N′-(4-Fluoro­benzyl­idene)-2-(4-fluoro­phen­yl)acetohydrazide Fun, Hoong-Kun Hemamalini, Madhukar Sumangala, V. Nagaraja, G. K. Poojary, Boja Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(12)F(2)N(2)O, the dihedral angle between the two benzene rings is 48.73 (8)°. The hydrazine group is twisted slightly, with a C—N—N—C torsion angle of 172.48 (12)°. In the crystal, mol­ecules are connected by strong N—H⋯O and weak C—H⋯O hydrogen bonds, forming supra­molecular chains along the c axis. The structure is consolidated by π–π [centroid–centroid separation = 3.6579 (10) Å] and C—H⋯π inter­actions. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3247574/ /pubmed/22219879 http://dx.doi.org/10.1107/S1600536811039845 Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Hemamalini, Madhukar
Sumangala, V.
Nagaraja, G. K.
Poojary, Boja
N′-(4-Fluoro­benzyl­idene)-2-(4-fluoro­phen­yl)acetohydrazide
title N′-(4-Fluoro­benzyl­idene)-2-(4-fluoro­phen­yl)acetohydrazide
title_full N′-(4-Fluoro­benzyl­idene)-2-(4-fluoro­phen­yl)acetohydrazide
title_fullStr N′-(4-Fluoro­benzyl­idene)-2-(4-fluoro­phen­yl)acetohydrazide
title_full_unstemmed N′-(4-Fluoro­benzyl­idene)-2-(4-fluoro­phen­yl)acetohydrazide
title_short N′-(4-Fluoro­benzyl­idene)-2-(4-fluoro­phen­yl)acetohydrazide
title_sort n′-(4-fluoro­benzyl­idene)-2-(4-fluoro­phen­yl)acetohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247574/
https://www.ncbi.nlm.nih.gov/pubmed/22219879
http://dx.doi.org/10.1107/S1600536811039845
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