6-Bromo­imidazo[1,2-a]pyridin-8-amine

The title compound, C(7)H(6)BrN(3), crystallizes with three independent mol­ecules in the asymmetric unit. The mol­ecules are approximately planar (r.m.s. deviations for all non-H atoms = 0.016, 0.023 and 0.024 Å). The primary amine groups show pyramidal coordination. In the crystal, adjacent mol­ec...

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Autores principales: Dahmani, Siham, Kandri Rodi, Youssef, Capet, Frederic, Essassi, El Mokhtar, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247577/
https://www.ncbi.nlm.nih.gov/pubmed/22219882
http://dx.doi.org/10.1107/S1600536811040177
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author Dahmani, Siham
Kandri Rodi, Youssef
Capet, Frederic
Essassi, El Mokhtar
Ng, Seik Weng
author_facet Dahmani, Siham
Kandri Rodi, Youssef
Capet, Frederic
Essassi, El Mokhtar
Ng, Seik Weng
author_sort Dahmani, Siham
collection PubMed
description The title compound, C(7)H(6)BrN(3), crystallizes with three independent mol­ecules in the asymmetric unit. The mol­ecules are approximately planar (r.m.s. deviations for all non-H atoms = 0.016, 0.023 and 0.024 Å). The primary amine groups show pyramidal coordination. In the crystal, adjacent mol­ecules are linked by N—H⋯N hydrogen bonds. For two independent mol­ecules, the amine groups are hydrogen-bond donors via one H atom to one acceptor atom, whereas for the third independent mol­ecule, the amine group is a hydrogen-bond donor to two acceptor atoms.
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spelling pubmed-32475772012-01-04 6-Bromo­imidazo[1,2-a]pyridin-8-amine Dahmani, Siham Kandri Rodi, Youssef Capet, Frederic Essassi, El Mokhtar Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(7)H(6)BrN(3), crystallizes with three independent mol­ecules in the asymmetric unit. The mol­ecules are approximately planar (r.m.s. deviations for all non-H atoms = 0.016, 0.023 and 0.024 Å). The primary amine groups show pyramidal coordination. In the crystal, adjacent mol­ecules are linked by N—H⋯N hydrogen bonds. For two independent mol­ecules, the amine groups are hydrogen-bond donors via one H atom to one acceptor atom, whereas for the third independent mol­ecule, the amine group is a hydrogen-bond donor to two acceptor atoms. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3247577/ /pubmed/22219882 http://dx.doi.org/10.1107/S1600536811040177 Text en © Dahmani et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dahmani, Siham
Kandri Rodi, Youssef
Capet, Frederic
Essassi, El Mokhtar
Ng, Seik Weng
6-Bromo­imidazo[1,2-a]pyridin-8-amine
title 6-Bromo­imidazo[1,2-a]pyridin-8-amine
title_full 6-Bromo­imidazo[1,2-a]pyridin-8-amine
title_fullStr 6-Bromo­imidazo[1,2-a]pyridin-8-amine
title_full_unstemmed 6-Bromo­imidazo[1,2-a]pyridin-8-amine
title_short 6-Bromo­imidazo[1,2-a]pyridin-8-amine
title_sort 6-bromo­imidazo[1,2-a]pyridin-8-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247577/
https://www.ncbi.nlm.nih.gov/pubmed/22219882
http://dx.doi.org/10.1107/S1600536811040177
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AT essassielmokhtar 6bromoimidazo12apyridin8amine
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