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Dicyclo­hexyl­ammonium thio­cyanate: monoclinic polymorph

The title salt, C(12)H(24)N(+)·NCS(−), represents a monoclinic polymorph of the previously reported ortho­rhom­bic form [Khawar Rauf et al. (2008 ▶). Acta Cryst. E64, o366]. Two independent formula units comprise the asymmetric unit with the major difference in their mol­ecular structures relating t...

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Detalles Bibliográficos
Autores principales: Selvakumaran, N., Karvembu, R., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247581/
https://www.ncbi.nlm.nih.gov/pubmed/22219886
http://dx.doi.org/10.1107/S1600536811040001
Descripción
Sumario:The title salt, C(12)H(24)N(+)·NCS(−), represents a monoclinic polymorph of the previously reported ortho­rhom­bic form [Khawar Rauf et al. (2008 ▶). Acta Cryst. E64, o366]. Two independent formula units comprise the asymmetric unit with the major difference in their mol­ecular structures relating to the relative dispositions of the cyclo­hexyl rings [dihedral angles = 79.88 (6) and 67.72 (5)°]. Further, the independent anions form distinctive patterns of hydrogen-bonding inter­actions, i.e. 2 × N—H⋯N versus N—H⋯N and N—H⋯S. The resulting supra­molecular architecture is a supra­molecular chain along the c axis based on a square-wave topology.