(9R,10R,10aR)-9-(2-Bromo­phen­yl)-10-nitro-6-phenyl-10,10a-dihydro-9H-benzo[c]chromene-8-carbaldehyde

The title compound, C(26)H(18)BrNO(4), features a functionalized chromene. The cyclo­hexene ring adopts a sofa conformation and has the nitro group and the bromo­phenyl ring in an axial position. The ten atoms of the chromene moiety lie close to a common plane (r.m.s. deviation = 0.066 Å). The attac...

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Detalles Bibliográficos
Autores principales: Dufour, Jeremy, Maji, Modhu Sudan, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247582/
https://www.ncbi.nlm.nih.gov/pubmed/22219887
http://dx.doi.org/10.1107/S160053681103995X
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author Dufour, Jeremy
Maji, Modhu Sudan
Bolte, Michael
author_facet Dufour, Jeremy
Maji, Modhu Sudan
Bolte, Michael
author_sort Dufour, Jeremy
collection PubMed
description The title compound, C(26)H(18)BrNO(4), features a functionalized chromene. The cyclo­hexene ring adopts a sofa conformation and has the nitro group and the bromo­phenyl ring in an axial position. The ten atoms of the chromene moiety lie close to a common plane (r.m.s. deviation = 0.066 Å). The attached phenyl ring is twisted by 32.89 (10)° from the chromene plane. The crystal packing is stabilized by C—H⋯O inter­actions.
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spelling pubmed-32475822012-01-04 (9R,10R,10aR)-9-(2-Bromo­phen­yl)-10-nitro-6-phenyl-10,10a-dihydro-9H-benzo[c]chromene-8-carbaldehyde Dufour, Jeremy Maji, Modhu Sudan Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(26)H(18)BrNO(4), features a functionalized chromene. The cyclo­hexene ring adopts a sofa conformation and has the nitro group and the bromo­phenyl ring in an axial position. The ten atoms of the chromene moiety lie close to a common plane (r.m.s. deviation = 0.066 Å). The attached phenyl ring is twisted by 32.89 (10)° from the chromene plane. The crystal packing is stabilized by C—H⋯O inter­actions. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3247582/ /pubmed/22219887 http://dx.doi.org/10.1107/S160053681103995X Text en © Dufour et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dufour, Jeremy
Maji, Modhu Sudan
Bolte, Michael
(9R,10R,10aR)-9-(2-Bromo­phen­yl)-10-nitro-6-phenyl-10,10a-dihydro-9H-benzo[c]chromene-8-carbaldehyde
title (9R,10R,10aR)-9-(2-Bromo­phen­yl)-10-nitro-6-phenyl-10,10a-dihydro-9H-benzo[c]chromene-8-carbaldehyde
title_full (9R,10R,10aR)-9-(2-Bromo­phen­yl)-10-nitro-6-phenyl-10,10a-dihydro-9H-benzo[c]chromene-8-carbaldehyde
title_fullStr (9R,10R,10aR)-9-(2-Bromo­phen­yl)-10-nitro-6-phenyl-10,10a-dihydro-9H-benzo[c]chromene-8-carbaldehyde
title_full_unstemmed (9R,10R,10aR)-9-(2-Bromo­phen­yl)-10-nitro-6-phenyl-10,10a-dihydro-9H-benzo[c]chromene-8-carbaldehyde
title_short (9R,10R,10aR)-9-(2-Bromo­phen­yl)-10-nitro-6-phenyl-10,10a-dihydro-9H-benzo[c]chromene-8-carbaldehyde
title_sort (9r,10r,10ar)-9-(2-bromo­phen­yl)-10-nitro-6-phenyl-10,10a-dihydro-9h-benzo[c]chromene-8-carbaldehyde
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247582/
https://www.ncbi.nlm.nih.gov/pubmed/22219887
http://dx.doi.org/10.1107/S160053681103995X
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AT boltemichael 9r10r10ar92bromophenyl10nitro6phenyl1010adihydro9hbenzocchromene8carbaldehyde

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