N′-(4-Chloro­benzyl­idene)-2-[4-(methyl­sulfan­yl)phen­yl]acetohydrazide

In the title compound, C(16)H(15)ClN(2)OS, the hydrazine group is twisted slightly: the C—N—N—C torsion angle is 175.46 (13)°. The dihedral angle between the two terminal aromatic rings is 87.01 (8)°. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loop...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Hemamalini, Madhukar, Sumangala, V., Prasad, D. Jagadeesh, Poojary, Boja
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247585/
https://www.ncbi.nlm.nih.gov/pubmed/22219890
http://dx.doi.org/10.1107/S1600536811039857
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author Fun, Hoong-Kun
Hemamalini, Madhukar
Sumangala, V.
Prasad, D. Jagadeesh
Poojary, Boja
author_facet Fun, Hoong-Kun
Hemamalini, Madhukar
Sumangala, V.
Prasad, D. Jagadeesh
Poojary, Boja
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(16)H(15)ClN(2)OS, the hydrazine group is twisted slightly: the C—N—N—C torsion angle is 175.46 (13)°. The dihedral angle between the two terminal aromatic rings is 87.01 (8)°. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops. The dimers are further linked by weak C—H⋯π inter­actions.
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spelling pubmed-32475852012-01-04 N′-(4-Chloro­benzyl­idene)-2-[4-(methyl­sulfan­yl)phen­yl]acetohydrazide Fun, Hoong-Kun Hemamalini, Madhukar Sumangala, V. Prasad, D. Jagadeesh Poojary, Boja Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(15)ClN(2)OS, the hydrazine group is twisted slightly: the C—N—N—C torsion angle is 175.46 (13)°. The dihedral angle between the two terminal aromatic rings is 87.01 (8)°. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops. The dimers are further linked by weak C—H⋯π inter­actions. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3247585/ /pubmed/22219890 http://dx.doi.org/10.1107/S1600536811039857 Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Hemamalini, Madhukar
Sumangala, V.
Prasad, D. Jagadeesh
Poojary, Boja
N′-(4-Chloro­benzyl­idene)-2-[4-(methyl­sulfan­yl)phen­yl]acetohydrazide
title N′-(4-Chloro­benzyl­idene)-2-[4-(methyl­sulfan­yl)phen­yl]acetohydrazide
title_full N′-(4-Chloro­benzyl­idene)-2-[4-(methyl­sulfan­yl)phen­yl]acetohydrazide
title_fullStr N′-(4-Chloro­benzyl­idene)-2-[4-(methyl­sulfan­yl)phen­yl]acetohydrazide
title_full_unstemmed N′-(4-Chloro­benzyl­idene)-2-[4-(methyl­sulfan­yl)phen­yl]acetohydrazide
title_short N′-(4-Chloro­benzyl­idene)-2-[4-(methyl­sulfan­yl)phen­yl]acetohydrazide
title_sort n′-(4-chloro­benzyl­idene)-2-[4-(methyl­sulfan­yl)phen­yl]acetohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247585/
https://www.ncbi.nlm.nih.gov/pubmed/22219890
http://dx.doi.org/10.1107/S1600536811039857
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