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N,N′-Di-tert-butyl-N′′-(2-chloroacetyl)phosphoric triamide
The P atom in the title molecule, C(10)H(23)ClN(3)O(2)P, has a distorted tetrahedral coordination. In the C(O)NHP(O) unit, which has syn-oriented phosphoryl and N—H groups, the P—N bond of 1.703 (2) Å is longer and the O—P—N angle of 103.86 (7)° is contracted compared with the respective values in...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247586/ https://www.ncbi.nlm.nih.gov/pubmed/22219891 http://dx.doi.org/10.1107/S1600536811040773 |
Sumario: | The P atom in the title molecule, C(10)H(23)ClN(3)O(2)P, has a distorted tetrahedral coordination. In the C(O)NHP(O) unit, which has syn-oriented phosphoryl and N—H groups, the P—N bond of 1.703 (2) Å is longer and the O—P—N angle of 103.86 (7)° is contracted compared with the respective values in the two P(O)NHC(CH(3))(3) units [P—N = 1.632 (2) and 1.624 (2) Å; O—P—N = 116.80 (8) and 115.32 (8)°]. In the crystal, each molecule is hydrogen bonded to two adjacent molecules via N—H⋯O hydrogen bonds, forming a linear sequence of alternating R (2) (2)(8) and R (2) (2)(12)/R (2) (1)(6)-fused rings along [010]. The O atom of the carbonyl group acts as a double H-atom acceptor. |
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