N,N′-Di-tert-butyl-N′′-(2-chloro­acet­yl)phospho­ric triamide

The P atom in the title mol­ecule, C(10)H(23)ClN(3)O(2)P, has a distorted tetra­hedral coordination. In the C(O)NHP(O) unit, which has syn-oriented phosphoryl and N—H groups, the P—N bond of 1.703 (2) Å is longer and the O—P—N angle of 103.86 (7)° is contracted compared with the respective values in...

Descripción completa

Detalles Bibliográficos
Autores principales: Pourayoubi, Mehrdad, Elahi, Behrouz, Parvez, Masood
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247586/
https://www.ncbi.nlm.nih.gov/pubmed/22219891
http://dx.doi.org/10.1107/S1600536811040773
_version_ 1782220141163970560
author Pourayoubi, Mehrdad
Elahi, Behrouz
Parvez, Masood
author_facet Pourayoubi, Mehrdad
Elahi, Behrouz
Parvez, Masood
author_sort Pourayoubi, Mehrdad
collection PubMed
description The P atom in the title mol­ecule, C(10)H(23)ClN(3)O(2)P, has a distorted tetra­hedral coordination. In the C(O)NHP(O) unit, which has syn-oriented phosphoryl and N—H groups, the P—N bond of 1.703 (2) Å is longer and the O—P—N angle of 103.86 (7)° is contracted compared with the respective values in the two P(O)NHC(CH(3))(3) units [P—N = 1.632 (2) and 1.624 (2) Å; O—P—N = 116.80 (8) and 115.32 (8)°]. In the crystal, each mol­ecule is hydrogen bonded to two adjacent mol­ecules via N—H⋯O hydrogen bonds, forming a linear sequence of alternating R (2) (2)(8) and R (2) (2)(12)/R (2) (1)(6)-fused rings along [010]. The O atom of the carbonyl group acts as a double H-atom acceptor.
format Online
Article
Text
id pubmed-3247586
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32475862012-01-04 N,N′-Di-tert-butyl-N′′-(2-chloro­acet­yl)phospho­ric triamide Pourayoubi, Mehrdad Elahi, Behrouz Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers The P atom in the title mol­ecule, C(10)H(23)ClN(3)O(2)P, has a distorted tetra­hedral coordination. In the C(O)NHP(O) unit, which has syn-oriented phosphoryl and N—H groups, the P—N bond of 1.703 (2) Å is longer and the O—P—N angle of 103.86 (7)° is contracted compared with the respective values in the two P(O)NHC(CH(3))(3) units [P—N = 1.632 (2) and 1.624 (2) Å; O—P—N = 116.80 (8) and 115.32 (8)°]. In the crystal, each mol­ecule is hydrogen bonded to two adjacent mol­ecules via N—H⋯O hydrogen bonds, forming a linear sequence of alternating R (2) (2)(8) and R (2) (2)(12)/R (2) (1)(6)-fused rings along [010]. The O atom of the carbonyl group acts as a double H-atom acceptor. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3247586/ /pubmed/22219891 http://dx.doi.org/10.1107/S1600536811040773 Text en © Pourayoubi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pourayoubi, Mehrdad
Elahi, Behrouz
Parvez, Masood
N,N′-Di-tert-butyl-N′′-(2-chloro­acet­yl)phospho­ric triamide
title N,N′-Di-tert-butyl-N′′-(2-chloro­acet­yl)phospho­ric triamide
title_full N,N′-Di-tert-butyl-N′′-(2-chloro­acet­yl)phospho­ric triamide
title_fullStr N,N′-Di-tert-butyl-N′′-(2-chloro­acet­yl)phospho­ric triamide
title_full_unstemmed N,N′-Di-tert-butyl-N′′-(2-chloro­acet­yl)phospho­ric triamide
title_short N,N′-Di-tert-butyl-N′′-(2-chloro­acet­yl)phospho­ric triamide
title_sort n,n′-di-tert-butyl-n′′-(2-chloro­acet­yl)phospho­ric triamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247586/
https://www.ncbi.nlm.nih.gov/pubmed/22219891
http://dx.doi.org/10.1107/S1600536811040773
work_keys_str_mv AT pourayoubimehrdad nnditertbutyln2chloroacetylphosphorictriamide
AT elahibehrouz nnditertbutyln2chloroacetylphosphorictriamide
AT parvezmasood nnditertbutyln2chloroacetylphosphorictriamide

Ejemplares similares