N′-[(1E)-3-Bromo-5-chloro-2-hy­droxy­benzyl­idene]-4-tert-butyl­benzo­hydrazide ethanol monosolvate

In the title compound, C(18)H(18)BrClN(2)O(2)·C(2)H(6)O, the hy­droxy group forms an intra­molecular O—H⋯N hydrogen bond, which influences the conformation of the Shiff base mol­ecule, where the two aromatic rings form a dihedral angle of 21.67 (8)°. Inter­molecular N—H⋯O and O—H⋯O hydrogen bonds li...

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Detalles Bibliográficos
Autores principales: Thirugnanasundar, A., Parthipan, K., Anthonisamy, V. S. Xavier, Chakkaravarthi, G., Rajagopal, G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247593/
https://www.ncbi.nlm.nih.gov/pubmed/22219898
http://dx.doi.org/10.1107/S160053681104027X
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author Thirugnanasundar, A.
Parthipan, K.
Anthonisamy, V. S. Xavier
Chakkaravarthi, G.
Rajagopal, G.
author_facet Thirugnanasundar, A.
Parthipan, K.
Anthonisamy, V. S. Xavier
Chakkaravarthi, G.
Rajagopal, G.
author_sort Thirugnanasundar, A.
collection PubMed
description In the title compound, C(18)H(18)BrClN(2)O(2)·C(2)H(6)O, the hy­droxy group forms an intra­molecular O—H⋯N hydrogen bond, which influences the conformation of the Shiff base mol­ecule, where the two aromatic rings form a dihedral angle of 21.67 (8)°. Inter­molecular N—H⋯O and O—H⋯O hydrogen bonds link two Shiff base mol­ecules and two solvent mol­ecules into a centrosymmetric heterotetra­mer. Weak inter­molecular C—H⋯O inter­actions link further tetra­mers related by translation along the a axis into chains.
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spelling pubmed-32475932012-01-04 N′-[(1E)-3-Bromo-5-chloro-2-hy­droxy­benzyl­idene]-4-tert-butyl­benzo­hydrazide ethanol monosolvate Thirugnanasundar, A. Parthipan, K. Anthonisamy, V. S. Xavier Chakkaravarthi, G. Rajagopal, G. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(18)BrClN(2)O(2)·C(2)H(6)O, the hy­droxy group forms an intra­molecular O—H⋯N hydrogen bond, which influences the conformation of the Shiff base mol­ecule, where the two aromatic rings form a dihedral angle of 21.67 (8)°. Inter­molecular N—H⋯O and O—H⋯O hydrogen bonds link two Shiff base mol­ecules and two solvent mol­ecules into a centrosymmetric heterotetra­mer. Weak inter­molecular C—H⋯O inter­actions link further tetra­mers related by translation along the a axis into chains. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3247593/ /pubmed/22219898 http://dx.doi.org/10.1107/S160053681104027X Text en © Thirugnanasundar et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Thirugnanasundar, A.
Parthipan, K.
Anthonisamy, V. S. Xavier
Chakkaravarthi, G.
Rajagopal, G.
N′-[(1E)-3-Bromo-5-chloro-2-hy­droxy­benzyl­idene]-4-tert-butyl­benzo­hydrazide ethanol monosolvate
title N′-[(1E)-3-Bromo-5-chloro-2-hy­droxy­benzyl­idene]-4-tert-butyl­benzo­hydrazide ethanol monosolvate
title_full N′-[(1E)-3-Bromo-5-chloro-2-hy­droxy­benzyl­idene]-4-tert-butyl­benzo­hydrazide ethanol monosolvate
title_fullStr N′-[(1E)-3-Bromo-5-chloro-2-hy­droxy­benzyl­idene]-4-tert-butyl­benzo­hydrazide ethanol monosolvate
title_full_unstemmed N′-[(1E)-3-Bromo-5-chloro-2-hy­droxy­benzyl­idene]-4-tert-butyl­benzo­hydrazide ethanol monosolvate
title_short N′-[(1E)-3-Bromo-5-chloro-2-hy­droxy­benzyl­idene]-4-tert-butyl­benzo­hydrazide ethanol monosolvate
title_sort n′-[(1e)-3-bromo-5-chloro-2-hy­droxy­benzyl­idene]-4-tert-butyl­benzo­hydrazide ethanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247593/
https://www.ncbi.nlm.nih.gov/pubmed/22219898
http://dx.doi.org/10.1107/S160053681104027X
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