1-(5-Nitro-2-oxoindolin-3-yl­idene)thio­semicarbazide

In the title molecule, C(9)H(7)N(5)O(3)S, there is an intramolecular N—H⋯O. The molecule is essentially planar, with the maximum deviation from the mean plane of the 18 non-H atoms being 0.135 (2) Å for the amine N atom. In the crystal, the molecules are connected via intermolecular N—H⋯O and N—H⋯S...

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Autores principales: Bandeira, Katlen C. T., Bresolin, Leandro, Beck, Johannes, Daniels, Jörg, de Oliveira, Adriano Bof
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247594/
https://www.ncbi.nlm.nih.gov/pubmed/22219899
http://dx.doi.org/10.1107/S1600536811040293
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author Bandeira, Katlen C. T.
Bresolin, Leandro
Beck, Johannes
Daniels, Jörg
de Oliveira, Adriano Bof
author_facet Bandeira, Katlen C. T.
Bresolin, Leandro
Beck, Johannes
Daniels, Jörg
de Oliveira, Adriano Bof
author_sort Bandeira, Katlen C. T.
collection PubMed
description In the title molecule, C(9)H(7)N(5)O(3)S, there is an intramolecular N—H⋯O. The molecule is essentially planar, with the maximum deviation from the mean plane of the 18 non-H atoms being 0.135 (2) Å for the amine N atom. In the crystal, the molecules are connected via intermolecular N—H⋯O and N—H⋯S hydrogen bonds, forming two-dimensional networks lying parallel to (10[Image: see text]). They are separated by an interplanar distance of 3.3214 (9) Å, leading to π–π interactions which stabilize the crystal structure.
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spelling pubmed-32475942012-01-04 1-(5-Nitro-2-oxoindolin-3-yl­idene)thio­semicarbazide Bandeira, Katlen C. T. Bresolin, Leandro Beck, Johannes Daniels, Jörg de Oliveira, Adriano Bof Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(9)H(7)N(5)O(3)S, there is an intramolecular N—H⋯O. The molecule is essentially planar, with the maximum deviation from the mean plane of the 18 non-H atoms being 0.135 (2) Å for the amine N atom. In the crystal, the molecules are connected via intermolecular N—H⋯O and N—H⋯S hydrogen bonds, forming two-dimensional networks lying parallel to (10[Image: see text]). They are separated by an interplanar distance of 3.3214 (9) Å, leading to π–π interactions which stabilize the crystal structure. International Union of Crystallography 2011-10-05 /pmc/articles/PMC3247594/ /pubmed/22219899 http://dx.doi.org/10.1107/S1600536811040293 Text en © Bandeira et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bandeira, Katlen C. T.
Bresolin, Leandro
Beck, Johannes
Daniels, Jörg
de Oliveira, Adriano Bof
1-(5-Nitro-2-oxoindolin-3-yl­idene)thio­semicarbazide
title 1-(5-Nitro-2-oxoindolin-3-yl­idene)thio­semicarbazide
title_full 1-(5-Nitro-2-oxoindolin-3-yl­idene)thio­semicarbazide
title_fullStr 1-(5-Nitro-2-oxoindolin-3-yl­idene)thio­semicarbazide
title_full_unstemmed 1-(5-Nitro-2-oxoindolin-3-yl­idene)thio­semicarbazide
title_short 1-(5-Nitro-2-oxoindolin-3-yl­idene)thio­semicarbazide
title_sort 1-(5-nitro-2-oxoindolin-3-yl­idene)thio­semicarbazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247594/
https://www.ncbi.nlm.nih.gov/pubmed/22219899
http://dx.doi.org/10.1107/S1600536811040293
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