5-[(E)-Benzyl­idene]-2-hy­droxy-8,9-di­phenyl-3,10-diaza­hexa­cyclo­[10.7.1.1(3,7).0(2,11).0(7,11).0(16,20)]henicosa-1(19),12(20),13,15,17-pentaen-6-one

In the title compound, C(38)H(30)N(2)O(2), the acenaphthyl­ene ring is close to being planar [maximum deviation = 0.1047 (11) Å]. The dihedral angles between the three benzene rings and the acenaphthyl­ene system are 39.47 (3), 37.65 (3) and 44.47 (3)°. An intra­molecular O—H⋯N inter­action forms an...

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Detalles Bibliográficos
Autores principales: Kumar, Raju Suresh, Osman, Hasnah, Kia, Yalda, Rosli, Mohd Mustaqim, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247611/
https://www.ncbi.nlm.nih.gov/pubmed/22219916
http://dx.doi.org/10.1107/S1600536811040645
Descripción
Sumario:In the title compound, C(38)H(30)N(2)O(2), the acenaphthyl­ene ring is close to being planar [maximum deviation = 0.1047 (11) Å]. The dihedral angles between the three benzene rings and the acenaphthyl­ene system are 39.47 (3), 37.65 (3) and 44.47 (3)°. An intra­molecular O—H⋯N inter­action forms an S(5) hydrogen-bond ring motif. In the crystal, mol­ecules are linked into [101] chains by a set of C—H⋯O inter­actions.

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