5-[(E)-Benzyl­idene]-2-hy­droxy-8,9-di­phenyl-3,10-diaza­hexa­cyclo­[10.7.1.1(3,7).0(2,11).0(7,11).0(16,20)]henicosa-1(19),12(20),13,15,17-pentaen-6-one

In the title compound, C(38)H(30)N(2)O(2), the acenaphthyl­ene ring is close to being planar [maximum deviation = 0.1047 (11) Å]. The dihedral angles between the three benzene rings and the acenaphthyl­ene system are 39.47 (3), 37.65 (3) and 44.47 (3)°. An intra­molecular O—H⋯N inter­action forms an...

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Detalles Bibliográficos
Autores principales: Kumar, Raju Suresh, Osman, Hasnah, Kia, Yalda, Rosli, Mohd Mustaqim, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247611/
https://www.ncbi.nlm.nih.gov/pubmed/22219916
http://dx.doi.org/10.1107/S1600536811040645
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author Kumar, Raju Suresh
Osman, Hasnah
Kia, Yalda
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_facet Kumar, Raju Suresh
Osman, Hasnah
Kia, Yalda
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
author_sort Kumar, Raju Suresh
collection PubMed
description In the title compound, C(38)H(30)N(2)O(2), the acenaphthyl­ene ring is close to being planar [maximum deviation = 0.1047 (11) Å]. The dihedral angles between the three benzene rings and the acenaphthyl­ene system are 39.47 (3), 37.65 (3) and 44.47 (3)°. An intra­molecular O—H⋯N inter­action forms an S(5) hydrogen-bond ring motif. In the crystal, mol­ecules are linked into [101] chains by a set of C—H⋯O inter­actions.
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spelling pubmed-32476112012-01-04 5-[(E)-Benzyl­idene]-2-hy­droxy-8,9-di­phenyl-3,10-diaza­hexa­cyclo­[10.7.1.1(3,7).0(2,11).0(7,11).0(16,20)]henicosa-1(19),12(20),13,15,17-pentaen-6-one Kumar, Raju Suresh Osman, Hasnah Kia, Yalda Rosli, Mohd Mustaqim Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(38)H(30)N(2)O(2), the acenaphthyl­ene ring is close to being planar [maximum deviation = 0.1047 (11) Å]. The dihedral angles between the three benzene rings and the acenaphthyl­ene system are 39.47 (3), 37.65 (3) and 44.47 (3)°. An intra­molecular O—H⋯N inter­action forms an S(5) hydrogen-bond ring motif. In the crystal, mol­ecules are linked into [101] chains by a set of C—H⋯O inter­actions. International Union of Crystallography 2011-10-08 /pmc/articles/PMC3247611/ /pubmed/22219916 http://dx.doi.org/10.1107/S1600536811040645 Text en © Kumar et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kumar, Raju Suresh
Osman, Hasnah
Kia, Yalda
Rosli, Mohd Mustaqim
Fun, Hoong-Kun
5-[(E)-Benzyl­idene]-2-hy­droxy-8,9-di­phenyl-3,10-diaza­hexa­cyclo­[10.7.1.1(3,7).0(2,11).0(7,11).0(16,20)]henicosa-1(19),12(20),13,15,17-pentaen-6-one
title 5-[(E)-Benzyl­idene]-2-hy­droxy-8,9-di­phenyl-3,10-diaza­hexa­cyclo­[10.7.1.1(3,7).0(2,11).0(7,11).0(16,20)]henicosa-1(19),12(20),13,15,17-pentaen-6-one
title_full 5-[(E)-Benzyl­idene]-2-hy­droxy-8,9-di­phenyl-3,10-diaza­hexa­cyclo­[10.7.1.1(3,7).0(2,11).0(7,11).0(16,20)]henicosa-1(19),12(20),13,15,17-pentaen-6-one
title_fullStr 5-[(E)-Benzyl­idene]-2-hy­droxy-8,9-di­phenyl-3,10-diaza­hexa­cyclo­[10.7.1.1(3,7).0(2,11).0(7,11).0(16,20)]henicosa-1(19),12(20),13,15,17-pentaen-6-one
title_full_unstemmed 5-[(E)-Benzyl­idene]-2-hy­droxy-8,9-di­phenyl-3,10-diaza­hexa­cyclo­[10.7.1.1(3,7).0(2,11).0(7,11).0(16,20)]henicosa-1(19),12(20),13,15,17-pentaen-6-one
title_short 5-[(E)-Benzyl­idene]-2-hy­droxy-8,9-di­phenyl-3,10-diaza­hexa­cyclo­[10.7.1.1(3,7).0(2,11).0(7,11).0(16,20)]henicosa-1(19),12(20),13,15,17-pentaen-6-one
title_sort 5-[(e)-benzyl­idene]-2-hy­droxy-8,9-di­phenyl-3,10-diaza­hexa­cyclo­[10.7.1.1(3,7).0(2,11).0(7,11).0(16,20)]henicosa-1(19),12(20),13,15,17-pentaen-6-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247611/
https://www.ncbi.nlm.nih.gov/pubmed/22219916
http://dx.doi.org/10.1107/S1600536811040645
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