(5E)-5-(2,4-Dichloro­benzyl­idene)-2-(piperidin-1-yl)-1,3-thia­zol-4(5H)-one

In the title compound, C(15)H(14)Cl(2)N(2)OS, the piperidine ring adopts a chair conformation. The dihedral angle between the thia­zolidine ring and the dichloro­benzene ring is 9.30 (4)°; this near coplanar conformation is stabilized by the formation of an intra­molecular C—H⋯S hydrogen bond, which...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Hemamalini, Madhukar, Lobo, Prajwal L., Prasad, D. Jagadeesh, Poojary, Boja
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247615/
https://www.ncbi.nlm.nih.gov/pubmed/22219920
http://dx.doi.org/10.1107/S1600536811040785
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author Fun, Hoong-Kun
Hemamalini, Madhukar
Lobo, Prajwal L.
Prasad, D. Jagadeesh
Poojary, Boja
author_facet Fun, Hoong-Kun
Hemamalini, Madhukar
Lobo, Prajwal L.
Prasad, D. Jagadeesh
Poojary, Boja
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(15)H(14)Cl(2)N(2)OS, the piperidine ring adopts a chair conformation. The dihedral angle between the thia­zolidine ring and the dichloro­benzene ring is 9.30 (4)°; this near coplanar conformation is stabilized by the formation of an intra­molecular C—H⋯S hydrogen bond, which generates an S(6) ring. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, forming [001] chains. Weak π–π inter­actions [centroid–centroid separation = 3.5460 (5) Å] consolidate the structure.
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spelling pubmed-32476152012-01-04 (5E)-5-(2,4-Dichloro­benzyl­idene)-2-(piperidin-1-yl)-1,3-thia­zol-4(5H)-one Fun, Hoong-Kun Hemamalini, Madhukar Lobo, Prajwal L. Prasad, D. Jagadeesh Poojary, Boja Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(14)Cl(2)N(2)OS, the piperidine ring adopts a chair conformation. The dihedral angle between the thia­zolidine ring and the dichloro­benzene ring is 9.30 (4)°; this near coplanar conformation is stabilized by the formation of an intra­molecular C—H⋯S hydrogen bond, which generates an S(6) ring. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, forming [001] chains. Weak π–π inter­actions [centroid–centroid separation = 3.5460 (5) Å] consolidate the structure. International Union of Crystallography 2011-10-08 /pmc/articles/PMC3247615/ /pubmed/22219920 http://dx.doi.org/10.1107/S1600536811040785 Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Hemamalini, Madhukar
Lobo, Prajwal L.
Prasad, D. Jagadeesh
Poojary, Boja
(5E)-5-(2,4-Dichloro­benzyl­idene)-2-(piperidin-1-yl)-1,3-thia­zol-4(5H)-one
title (5E)-5-(2,4-Dichloro­benzyl­idene)-2-(piperidin-1-yl)-1,3-thia­zol-4(5H)-one
title_full (5E)-5-(2,4-Dichloro­benzyl­idene)-2-(piperidin-1-yl)-1,3-thia­zol-4(5H)-one
title_fullStr (5E)-5-(2,4-Dichloro­benzyl­idene)-2-(piperidin-1-yl)-1,3-thia­zol-4(5H)-one
title_full_unstemmed (5E)-5-(2,4-Dichloro­benzyl­idene)-2-(piperidin-1-yl)-1,3-thia­zol-4(5H)-one
title_short (5E)-5-(2,4-Dichloro­benzyl­idene)-2-(piperidin-1-yl)-1,3-thia­zol-4(5H)-one
title_sort (5e)-5-(2,4-dichloro­benzyl­idene)-2-(piperidin-1-yl)-1,3-thia­zol-4(5h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247615/
https://www.ncbi.nlm.nih.gov/pubmed/22219920
http://dx.doi.org/10.1107/S1600536811040785
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