1,5-Anhydro-3,6-di-O-benzyl-2-de­oxy-1,2-C-dichloro­methyl­ene-d-glycero-d-gulo-hexitol

In the title compound, C(21)H(22)Cl(2)O(4), the pyranosyl ring adopts a twist-boat conformation with the O-benzyl groups in equatorial positions. In the crystal, O—H⋯O hydrogen bonding results in infinite chains of mol­ecules along [100]. The structure is further consolidated by weak C—H⋯O, C—H⋯Cl a...

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Detalles Bibliográficos
Autores principales: Kinfe, Henok H., Aderibigbe, Blessing A., Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247618/
https://www.ncbi.nlm.nih.gov/pubmed/22219923
http://dx.doi.org/10.1107/S1600536811040815
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author Kinfe, Henok H.
Aderibigbe, Blessing A.
Muller, Alfred
author_facet Kinfe, Henok H.
Aderibigbe, Blessing A.
Muller, Alfred
author_sort Kinfe, Henok H.
collection PubMed
description In the title compound, C(21)H(22)Cl(2)O(4), the pyranosyl ring adopts a twist-boat conformation with the O-benzyl groups in equatorial positions. In the crystal, O—H⋯O hydrogen bonding results in infinite chains of mol­ecules along [100]. The structure is further consolidated by weak C—H⋯O, C—H⋯Cl and C—H⋯π inter­actions. The absolute structure was determined.
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spelling pubmed-32476182012-01-04 1,5-Anhydro-3,6-di-O-benzyl-2-de­oxy-1,2-C-dichloro­methyl­ene-d-glycero-d-gulo-hexitol Kinfe, Henok H. Aderibigbe, Blessing A. Muller, Alfred Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(22)Cl(2)O(4), the pyranosyl ring adopts a twist-boat conformation with the O-benzyl groups in equatorial positions. In the crystal, O—H⋯O hydrogen bonding results in infinite chains of mol­ecules along [100]. The structure is further consolidated by weak C—H⋯O, C—H⋯Cl and C—H⋯π inter­actions. The absolute structure was determined. International Union of Crystallography 2011-10-08 /pmc/articles/PMC3247618/ /pubmed/22219923 http://dx.doi.org/10.1107/S1600536811040815 Text en © Kinfe et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kinfe, Henok H.
Aderibigbe, Blessing A.
Muller, Alfred
1,5-Anhydro-3,6-di-O-benzyl-2-de­oxy-1,2-C-dichloro­methyl­ene-d-glycero-d-gulo-hexitol
title 1,5-Anhydro-3,6-di-O-benzyl-2-de­oxy-1,2-C-dichloro­methyl­ene-d-glycero-d-gulo-hexitol
title_full 1,5-Anhydro-3,6-di-O-benzyl-2-de­oxy-1,2-C-dichloro­methyl­ene-d-glycero-d-gulo-hexitol
title_fullStr 1,5-Anhydro-3,6-di-O-benzyl-2-de­oxy-1,2-C-dichloro­methyl­ene-d-glycero-d-gulo-hexitol
title_full_unstemmed 1,5-Anhydro-3,6-di-O-benzyl-2-de­oxy-1,2-C-dichloro­methyl­ene-d-glycero-d-gulo-hexitol
title_short 1,5-Anhydro-3,6-di-O-benzyl-2-de­oxy-1,2-C-dichloro­methyl­ene-d-glycero-d-gulo-hexitol
title_sort 1,5-anhydro-3,6-di-o-benzyl-2-de­oxy-1,2-c-dichloro­methyl­ene-d-glycero-d-gulo-hexitol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247618/
https://www.ncbi.nlm.nih.gov/pubmed/22219923
http://dx.doi.org/10.1107/S1600536811040815
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AT mulleralfred 15anhydro36diobenzyl2deoxy12cdichloromethylenedglycerodgulohexitol

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