1,3-Bis(2-meth­oxy­phen­yl)thio­urea

In the title compound, C(15)H(16)N(2)O(2)S, the N–C(=S) bond lengths are indicative of the presence of amide-type resonance. The dihedral angles between the thio­urea unit and the attached aromatic rings are 59.80 (5) and 73.41 (4)° while the dihedral angle between the rings is 56.83 (4)°. In the cr...

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Detalles Bibliográficos
Autores principales: van Rooyen, Jason, Betz, Richard, van Brecht, Bernardus J. A. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247619/
https://www.ncbi.nlm.nih.gov/pubmed/22219924
http://dx.doi.org/10.1107/S1600536811040852
Descripción
Sumario:In the title compound, C(15)H(16)N(2)O(2)S, the N–C(=S) bond lengths are indicative of the presence of amide-type resonance. The dihedral angles between the thio­urea unit and the attached aromatic rings are 59.80 (5) and 73.41 (4)° while the dihedral angle between the rings is 56.83 (4)°. In the crystal, inversion dimers linked by pairs of N—H⋯S hydrogen bonds occur. An N—H⋯π inter­action is observed for the second amino group. The shortest centroid–centroid distance between two aromatic systems is 4.0958 (8) Å.

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