1,3-Bis(2-meth­oxy­phen­yl)thio­urea

In the title compound, C(15)H(16)N(2)O(2)S, the N–C(=S) bond lengths are indicative of the presence of amide-type resonance. The dihedral angles between the thio­urea unit and the attached aromatic rings are 59.80 (5) and 73.41 (4)° while the dihedral angle between the rings is 56.83 (4)°. In the cr...

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Detalles Bibliográficos
Autores principales: van Rooyen, Jason, Betz, Richard, van Brecht, Bernardus J. A. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247619/
https://www.ncbi.nlm.nih.gov/pubmed/22219924
http://dx.doi.org/10.1107/S1600536811040852
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author van Rooyen, Jason
Betz, Richard
van Brecht, Bernardus J. A. M.
author_facet van Rooyen, Jason
Betz, Richard
van Brecht, Bernardus J. A. M.
author_sort van Rooyen, Jason
collection PubMed
description In the title compound, C(15)H(16)N(2)O(2)S, the N–C(=S) bond lengths are indicative of the presence of amide-type resonance. The dihedral angles between the thio­urea unit and the attached aromatic rings are 59.80 (5) and 73.41 (4)° while the dihedral angle between the rings is 56.83 (4)°. In the crystal, inversion dimers linked by pairs of N—H⋯S hydrogen bonds occur. An N—H⋯π inter­action is observed for the second amino group. The shortest centroid–centroid distance between two aromatic systems is 4.0958 (8) Å.
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spelling pubmed-32476192012-01-04 1,3-Bis(2-meth­oxy­phen­yl)thio­urea van Rooyen, Jason Betz, Richard van Brecht, Bernardus J. A. M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(16)N(2)O(2)S, the N–C(=S) bond lengths are indicative of the presence of amide-type resonance. The dihedral angles between the thio­urea unit and the attached aromatic rings are 59.80 (5) and 73.41 (4)° while the dihedral angle between the rings is 56.83 (4)°. In the crystal, inversion dimers linked by pairs of N—H⋯S hydrogen bonds occur. An N—H⋯π inter­action is observed for the second amino group. The shortest centroid–centroid distance between two aromatic systems is 4.0958 (8) Å. International Union of Crystallography 2011-10-08 /pmc/articles/PMC3247619/ /pubmed/22219924 http://dx.doi.org/10.1107/S1600536811040852 Text en © Rooyen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
van Rooyen, Jason
Betz, Richard
van Brecht, Bernardus J. A. M.
1,3-Bis(2-meth­oxy­phen­yl)thio­urea
title 1,3-Bis(2-meth­oxy­phen­yl)thio­urea
title_full 1,3-Bis(2-meth­oxy­phen­yl)thio­urea
title_fullStr 1,3-Bis(2-meth­oxy­phen­yl)thio­urea
title_full_unstemmed 1,3-Bis(2-meth­oxy­phen­yl)thio­urea
title_short 1,3-Bis(2-meth­oxy­phen­yl)thio­urea
title_sort 1,3-bis(2-meth­oxy­phen­yl)thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247619/
https://www.ncbi.nlm.nih.gov/pubmed/22219924
http://dx.doi.org/10.1107/S1600536811040852
work_keys_str_mv AT vanrooyenjason 13bis2methoxyphenylthiourea
AT betzrichard 13bis2methoxyphenylthiourea
AT vanbrechtbernardusjam 13bis2methoxyphenylthiourea

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