Synthesis of dye/fluorescent functionalized dendrons based on cyclotriphosphazene

Functionalized phenols based on tyramine were synthesized in order to be selectively grafted on to hexachlorocyclotriphosphazene, affording a variety of functionalized dendrons of type AB(5). The B functions comprised fluorescent groups (dansyl) or dyes (dabsyl), whereas the A function was provided...

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Autores principales: Hameau, Aurélien, Fuchs, Sabine, Laurent, Régis, Majoral, Jean-Pierre, Caminade, Anne-Marie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3252861/
https://www.ncbi.nlm.nih.gov/pubmed/22238535
http://dx.doi.org/10.3762/bjoc.7.186
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author Hameau, Aurélien
Fuchs, Sabine
Laurent, Régis
Majoral, Jean-Pierre
Caminade, Anne-Marie
author_facet Hameau, Aurélien
Fuchs, Sabine
Laurent, Régis
Majoral, Jean-Pierre
Caminade, Anne-Marie
author_sort Hameau, Aurélien
collection PubMed
description Functionalized phenols based on tyramine were synthesized in order to be selectively grafted on to hexachlorocyclotriphosphazene, affording a variety of functionalized dendrons of type AB(5). The B functions comprised fluorescent groups (dansyl) or dyes (dabsyl), whereas the A function was provided by either an aldehyde or an amine. The characterization of these dendrons is reported. An unexpected behaviour of a fluorescent and water-soluble dendron based on dansyl groups in mixtures of dioxane/water was observed.
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spelling pubmed-32528612012-01-11 Synthesis of dye/fluorescent functionalized dendrons based on cyclotriphosphazene Hameau, Aurélien Fuchs, Sabine Laurent, Régis Majoral, Jean-Pierre Caminade, Anne-Marie Beilstein J Org Chem Full Research Paper Functionalized phenols based on tyramine were synthesized in order to be selectively grafted on to hexachlorocyclotriphosphazene, affording a variety of functionalized dendrons of type AB(5). The B functions comprised fluorescent groups (dansyl) or dyes (dabsyl), whereas the A function was provided by either an aldehyde or an amine. The characterization of these dendrons is reported. An unexpected behaviour of a fluorescent and water-soluble dendron based on dansyl groups in mixtures of dioxane/water was observed. Beilstein-Institut 2011-11-28 /pmc/articles/PMC3252861/ /pubmed/22238535 http://dx.doi.org/10.3762/bjoc.7.186 Text en Copyright © 2011, Hameau et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Hameau, Aurélien
Fuchs, Sabine
Laurent, Régis
Majoral, Jean-Pierre
Caminade, Anne-Marie
Synthesis of dye/fluorescent functionalized dendrons based on cyclotriphosphazene
title Synthesis of dye/fluorescent functionalized dendrons based on cyclotriphosphazene
title_full Synthesis of dye/fluorescent functionalized dendrons based on cyclotriphosphazene
title_fullStr Synthesis of dye/fluorescent functionalized dendrons based on cyclotriphosphazene
title_full_unstemmed Synthesis of dye/fluorescent functionalized dendrons based on cyclotriphosphazene
title_short Synthesis of dye/fluorescent functionalized dendrons based on cyclotriphosphazene
title_sort synthesis of dye/fluorescent functionalized dendrons based on cyclotriphosphazene
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3252861/
https://www.ncbi.nlm.nih.gov/pubmed/22238535
http://dx.doi.org/10.3762/bjoc.7.186
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