Recent advances in direct C–H arylation: Methodology, selectivity and mechanism in oxazole series

Catalytic direct (hetero)arylation of (hetero)arenes is an attractive alternative to traditional Kumada, Stille, Negishi and Suzuki–Miyaura cross-coupling reactions, notably as it avoids the prior preparation and isolation of (hetero)arylmetals. Developments of this methodology in the oxazole series...

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Detalles Bibliográficos
Autores principales: Verrier, Cécile, Lassalas, Pierrik, Théveau, Laure, Quéguiner, Guy, Trécourt, François, Marsais, Francis, Hoarau, Christophe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2011
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3252862/
https://www.ncbi.nlm.nih.gov/pubmed/22238536
http://dx.doi.org/10.3762/bjoc.7.187
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author Verrier, Cécile
Lassalas, Pierrik
Théveau, Laure
Quéguiner, Guy
Trécourt, François
Marsais, Francis
Hoarau, Christophe
author_facet Verrier, Cécile
Lassalas, Pierrik
Théveau, Laure
Quéguiner, Guy
Trécourt, François
Marsais, Francis
Hoarau, Christophe
author_sort Verrier, Cécile
collection PubMed
description Catalytic direct (hetero)arylation of (hetero)arenes is an attractive alternative to traditional Kumada, Stille, Negishi and Suzuki–Miyaura cross-coupling reactions, notably as it avoids the prior preparation and isolation of (hetero)arylmetals. Developments of this methodology in the oxazole series are reviewed in this article. Methodologies, selectivity, mechanism and future aspects are presented.
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spelling pubmed-32528622012-01-11 Recent advances in direct C–H arylation: Methodology, selectivity and mechanism in oxazole series Verrier, Cécile Lassalas, Pierrik Théveau, Laure Quéguiner, Guy Trécourt, François Marsais, Francis Hoarau, Christophe Beilstein J Org Chem Review Catalytic direct (hetero)arylation of (hetero)arenes is an attractive alternative to traditional Kumada, Stille, Negishi and Suzuki–Miyaura cross-coupling reactions, notably as it avoids the prior preparation and isolation of (hetero)arylmetals. Developments of this methodology in the oxazole series are reviewed in this article. Methodologies, selectivity, mechanism and future aspects are presented. Beilstein-Institut 2011-11-29 /pmc/articles/PMC3252862/ /pubmed/22238536 http://dx.doi.org/10.3762/bjoc.7.187 Text en Copyright © 2011, Verrier et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Review
Verrier, Cécile
Lassalas, Pierrik
Théveau, Laure
Quéguiner, Guy
Trécourt, François
Marsais, Francis
Hoarau, Christophe
Recent advances in direct C–H arylation: Methodology, selectivity and mechanism in oxazole series
title Recent advances in direct C–H arylation: Methodology, selectivity and mechanism in oxazole series
title_full Recent advances in direct C–H arylation: Methodology, selectivity and mechanism in oxazole series
title_fullStr Recent advances in direct C–H arylation: Methodology, selectivity and mechanism in oxazole series
title_full_unstemmed Recent advances in direct C–H arylation: Methodology, selectivity and mechanism in oxazole series
title_short Recent advances in direct C–H arylation: Methodology, selectivity and mechanism in oxazole series
title_sort recent advances in direct c–h arylation: methodology, selectivity and mechanism in oxazole series
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3252862/
https://www.ncbi.nlm.nih.gov/pubmed/22238536
http://dx.doi.org/10.3762/bjoc.7.187
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