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Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))ethanamine-κN]zinc(II)

The amine title complex, [ZnCl(2)(C(7)H(13)N(3))], resulted from imine hydrolysis in a Schiff base compound. The Zn metal atom has a distorted tetra­hedral geometry with the most significant deviation identified in the magnitude of the N—Zn—N angle. This deviation stems from the participation of the...

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Autores principales: Guzei, Ilia A., Spencer, Lara C., Segapelo, Tebogo V., Darkwa, James
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3253618/
https://www.ncbi.nlm.nih.gov/pubmed/22247716
http://dx.doi.org/10.1107/S1600536811044217
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author Guzei, Ilia A.
Spencer, Lara C.
Segapelo, Tebogo V.
Darkwa, James
author_facet Guzei, Ilia A.
Spencer, Lara C.
Segapelo, Tebogo V.
Darkwa, James
author_sort Guzei, Ilia A.
collection PubMed
description The amine title complex, [ZnCl(2)(C(7)H(13)N(3))], resulted from imine hydrolysis in a Schiff base compound. The Zn metal atom has a distorted tetra­hedral geometry with the most significant deviation identified in the magnitude of the N—Zn—N angle. This deviation stems from the participation of the Zn and N atoms in a six-membered metallocyclic ring. The latter is in an approximate screw-boat conformation. Two strong N—H⋯Cl hydrogen bonds link the mol­ecules into ribbons propagating along the b-axis direction. The ribbons contain two second-order hydrogen-bonded motifs: a chain and a ring. The chain described by the graph set notation C (2) (2)(6) is formed by one hydrogen bond going in the forward direction (donor to acceptor) and the other in the backward direction (acceptor to donor). In the ring motif R (2) (2)(8), both hydrogen bonds propagate in the forward direction.
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spelling pubmed-32536182012-01-13 Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))ethanamine-κN]zinc(II) Guzei, Ilia A. Spencer, Lara C. Segapelo, Tebogo V. Darkwa, James Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The amine title complex, [ZnCl(2)(C(7)H(13)N(3))], resulted from imine hydrolysis in a Schiff base compound. The Zn metal atom has a distorted tetra­hedral geometry with the most significant deviation identified in the magnitude of the N—Zn—N angle. This deviation stems from the participation of the Zn and N atoms in a six-membered metallocyclic ring. The latter is in an approximate screw-boat conformation. Two strong N—H⋯Cl hydrogen bonds link the mol­ecules into ribbons propagating along the b-axis direction. The ribbons contain two second-order hydrogen-bonded motifs: a chain and a ring. The chain described by the graph set notation C (2) (2)(6) is formed by one hydrogen bond going in the forward direction (donor to acceptor) and the other in the backward direction (acceptor to donor). In the ring motif R (2) (2)(8), both hydrogen bonds propagate in the forward direction. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3253618/ /pubmed/22247716 http://dx.doi.org/10.1107/S1600536811044217 Text en © Guzei et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guzei, Ilia A.
Spencer, Lara C.
Segapelo, Tebogo V.
Darkwa, James
Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))ethanamine-κN]zinc(II)
title Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))ethanamine-κN]zinc(II)
title_full Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))ethanamine-κN]zinc(II)
title_fullStr Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))ethanamine-κN]zinc(II)
title_full_unstemmed Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))ethanamine-κN]zinc(II)
title_short Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))ethanamine-κN]zinc(II)
title_sort dichlorido[2-(3,5-dimethyl-1h-pyrazol-1-yl-κn (2))ethanamine-κn]zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3253618/
https://www.ncbi.nlm.nih.gov/pubmed/22247716
http://dx.doi.org/10.1107/S1600536811044217
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