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Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))ethanamine-κN]zinc(II)
The amine title complex, [ZnCl(2)(C(7)H(13)N(3))], resulted from imine hydrolysis in a Schiff base compound. The Zn metal atom has a distorted tetrahedral geometry with the most significant deviation identified in the magnitude of the N—Zn—N angle. This deviation stems from the participation of the...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3253618/ https://www.ncbi.nlm.nih.gov/pubmed/22247716 http://dx.doi.org/10.1107/S1600536811044217 |
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author | Guzei, Ilia A. Spencer, Lara C. Segapelo, Tebogo V. Darkwa, James |
author_facet | Guzei, Ilia A. Spencer, Lara C. Segapelo, Tebogo V. Darkwa, James |
author_sort | Guzei, Ilia A. |
collection | PubMed |
description | The amine title complex, [ZnCl(2)(C(7)H(13)N(3))], resulted from imine hydrolysis in a Schiff base compound. The Zn metal atom has a distorted tetrahedral geometry with the most significant deviation identified in the magnitude of the N—Zn—N angle. This deviation stems from the participation of the Zn and N atoms in a six-membered metallocyclic ring. The latter is in an approximate screw-boat conformation. Two strong N—H⋯Cl hydrogen bonds link the molecules into ribbons propagating along the b-axis direction. The ribbons contain two second-order hydrogen-bonded motifs: a chain and a ring. The chain described by the graph set notation C (2) (2)(6) is formed by one hydrogen bond going in the forward direction (donor to acceptor) and the other in the backward direction (acceptor to donor). In the ring motif R (2) (2)(8), both hydrogen bonds propagate in the forward direction. |
format | Online Article Text |
id | pubmed-3253618 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32536182012-01-13 Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))ethanamine-κN]zinc(II) Guzei, Ilia A. Spencer, Lara C. Segapelo, Tebogo V. Darkwa, James Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The amine title complex, [ZnCl(2)(C(7)H(13)N(3))], resulted from imine hydrolysis in a Schiff base compound. The Zn metal atom has a distorted tetrahedral geometry with the most significant deviation identified in the magnitude of the N—Zn—N angle. This deviation stems from the participation of the Zn and N atoms in a six-membered metallocyclic ring. The latter is in an approximate screw-boat conformation. Two strong N—H⋯Cl hydrogen bonds link the molecules into ribbons propagating along the b-axis direction. The ribbons contain two second-order hydrogen-bonded motifs: a chain and a ring. The chain described by the graph set notation C (2) (2)(6) is formed by one hydrogen bond going in the forward direction (donor to acceptor) and the other in the backward direction (acceptor to donor). In the ring motif R (2) (2)(8), both hydrogen bonds propagate in the forward direction. International Union of Crystallography 2011-10-29 /pmc/articles/PMC3253618/ /pubmed/22247716 http://dx.doi.org/10.1107/S1600536811044217 Text en © Guzei et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Guzei, Ilia A. Spencer, Lara C. Segapelo, Tebogo V. Darkwa, James Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))ethanamine-κN]zinc(II) |
title | Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))ethanamine-κN]zinc(II) |
title_full | Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))ethanamine-κN]zinc(II) |
title_fullStr | Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))ethanamine-κN]zinc(II) |
title_full_unstemmed | Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))ethanamine-κN]zinc(II) |
title_short | Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))ethanamine-κN]zinc(II) |
title_sort | dichlorido[2-(3,5-dimethyl-1h-pyrazol-1-yl-κn
(2))ethanamine-κn]zinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3253618/ https://www.ncbi.nlm.nih.gov/pubmed/22247716 http://dx.doi.org/10.1107/S1600536811044217 |
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