Bis(formato-κO)bis­[1-(pyridin-2-yl)ethanone oxime-κ(2) N,N′]nickel(II)

In the title compound, [Ni(HCOO)(2)(C(7)H(8)N(2)O)(2)], the Ni atom is six-coordinated by four N atoms from two oxime ligands and by two O atoms from two formate ions in a distorted octa­hedral geometry, with the oxime-N atoms mutually trans. The mol­ecular conformation is stabilized by intra­molecu...

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Detalles Bibliográficos
Autores principales: Li, Leilei, Qiu, Xiumin, Li, Dacheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254275/
https://www.ncbi.nlm.nih.gov/pubmed/22259326
http://dx.doi.org/10.1107/S1600536811050859
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author Li, Leilei
Qiu, Xiumin
Li, Dacheng
author_facet Li, Leilei
Qiu, Xiumin
Li, Dacheng
author_sort Li, Leilei
collection PubMed
description In the title compound, [Ni(HCOO)(2)(C(7)H(8)N(2)O)(2)], the Ni atom is six-coordinated by four N atoms from two oxime ligands and by two O atoms from two formate ions in a distorted octa­hedral geometry, with the oxime-N atoms mutually trans. The mol­ecular conformation is stabilized by intra­molecular O—H⋯O hydrogen bonds.
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spelling pubmed-32542752012-01-18 Bis(formato-κO)bis­[1-(pyridin-2-yl)ethanone oxime-κ(2) N,N′]nickel(II) Li, Leilei Qiu, Xiumin Li, Dacheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(HCOO)(2)(C(7)H(8)N(2)O)(2)], the Ni atom is six-coordinated by four N atoms from two oxime ligands and by two O atoms from two formate ions in a distorted octa­hedral geometry, with the oxime-N atoms mutually trans. The mol­ecular conformation is stabilized by intra­molecular O—H⋯O hydrogen bonds. International Union of Crystallography 2011-12-03 /pmc/articles/PMC3254275/ /pubmed/22259326 http://dx.doi.org/10.1107/S1600536811050859 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Leilei
Qiu, Xiumin
Li, Dacheng
Bis(formato-κO)bis­[1-(pyridin-2-yl)ethanone oxime-κ(2) N,N′]nickel(II)
title Bis(formato-κO)bis­[1-(pyridin-2-yl)ethanone oxime-κ(2) N,N′]nickel(II)
title_full Bis(formato-κO)bis­[1-(pyridin-2-yl)ethanone oxime-κ(2) N,N′]nickel(II)
title_fullStr Bis(formato-κO)bis­[1-(pyridin-2-yl)ethanone oxime-κ(2) N,N′]nickel(II)
title_full_unstemmed Bis(formato-κO)bis­[1-(pyridin-2-yl)ethanone oxime-κ(2) N,N′]nickel(II)
title_short Bis(formato-κO)bis­[1-(pyridin-2-yl)ethanone oxime-κ(2) N,N′]nickel(II)
title_sort bis(formato-κo)bis­[1-(pyridin-2-yl)ethanone oxime-κ(2) n,n′]nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254275/
https://www.ncbi.nlm.nih.gov/pubmed/22259326
http://dx.doi.org/10.1107/S1600536811050859
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AT qiuxiumin bisformatokobis1pyridin2ylethanoneoximek2nnnickelii
AT lidacheng bisformatokobis1pyridin2ylethanoneoximek2nnnickelii

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