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catena-Poly[[(8-aminoquinoline-κ(2) N,N′)cadmium]-di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-[(8-aminoquinoline-κ(2) N,N′)cadmium]-di-μ-chlorido]
In the title compound, [CdCl(NCS)(C(9)H(8)N(2))](n), the Cd(II) atom is in a distorted octahedral coordination environment defined by two chloride anions, two N atoms from an 8-aminoquinoline ligand, one N atom from one thiocyanate anion and one S atom from a symmetry-related thiocyanate anion....
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254276/ https://www.ncbi.nlm.nih.gov/pubmed/22259334 http://dx.doi.org/10.1107/S1600536811051373 |
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author | Xu, Heng Guo, Chang |
author_facet | Xu, Heng Guo, Chang |
author_sort | Xu, Heng |
collection | PubMed |
description | In the title compound, [CdCl(NCS)(C(9)H(8)N(2))](n), the Cd(II) atom is in a distorted octahedral coordination environment defined by two chloride anions, two N atoms from an 8-aminoquinoline ligand, one N atom from one thiocyanate anion and one S atom from a symmetry-related thiocyanate anion. Two Cd(II) atoms are bridged by two chloride anions, forming an inversion-related Cd(2)Cl(2) unit; these units are further linked through thiocyanate anions, leading to a chain structure extending parallel to [010]. Weak π–π stacking interactions with centroid–centroid distances of 3.430 (4) Å and an interplanar separation of 3.390 (3) Å between the pyridine and benzene rings link the chains into a two-dimensional network parallel to (10[Image: see text]). Weak intermolecular C—H⋯Cl hydrogen-bonding interactions help to consolidate the crystal packing. |
format | Online Article Text |
id | pubmed-3254276 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32542762012-01-18 catena-Poly[[(8-aminoquinoline-κ(2) N,N′)cadmium]-di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-[(8-aminoquinoline-κ(2) N,N′)cadmium]-di-μ-chlorido] Xu, Heng Guo, Chang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CdCl(NCS)(C(9)H(8)N(2))](n), the Cd(II) atom is in a distorted octahedral coordination environment defined by two chloride anions, two N atoms from an 8-aminoquinoline ligand, one N atom from one thiocyanate anion and one S atom from a symmetry-related thiocyanate anion. Two Cd(II) atoms are bridged by two chloride anions, forming an inversion-related Cd(2)Cl(2) unit; these units are further linked through thiocyanate anions, leading to a chain structure extending parallel to [010]. Weak π–π stacking interactions with centroid–centroid distances of 3.430 (4) Å and an interplanar separation of 3.390 (3) Å between the pyridine and benzene rings link the chains into a two-dimensional network parallel to (10[Image: see text]). Weak intermolecular C—H⋯Cl hydrogen-bonding interactions help to consolidate the crystal packing. International Union of Crystallography 2011-12-03 /pmc/articles/PMC3254276/ /pubmed/22259334 http://dx.doi.org/10.1107/S1600536811051373 Text en © Xu and Guo 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xu, Heng Guo, Chang catena-Poly[[(8-aminoquinoline-κ(2) N,N′)cadmium]-di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-[(8-aminoquinoline-κ(2) N,N′)cadmium]-di-μ-chlorido] |
title |
catena-Poly[[(8-aminoquinoline-κ(2)
N,N′)cadmium]-di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N-[(8-aminoquinoline-κ(2)
N,N′)cadmium]-di-μ-chlorido] |
title_full |
catena-Poly[[(8-aminoquinoline-κ(2)
N,N′)cadmium]-di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N-[(8-aminoquinoline-κ(2)
N,N′)cadmium]-di-μ-chlorido] |
title_fullStr |
catena-Poly[[(8-aminoquinoline-κ(2)
N,N′)cadmium]-di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N-[(8-aminoquinoline-κ(2)
N,N′)cadmium]-di-μ-chlorido] |
title_full_unstemmed |
catena-Poly[[(8-aminoquinoline-κ(2)
N,N′)cadmium]-di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N-[(8-aminoquinoline-κ(2)
N,N′)cadmium]-di-μ-chlorido] |
title_short |
catena-Poly[[(8-aminoquinoline-κ(2)
N,N′)cadmium]-di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N-[(8-aminoquinoline-κ(2)
N,N′)cadmium]-di-μ-chlorido] |
title_sort | catena-poly[[(8-aminoquinoline-κ(2)
n,n′)cadmium]-di-μ-thiocyanato-κ(2)
n:s;κ(2)
s:n-[(8-aminoquinoline-κ(2)
n,n′)cadmium]-di-μ-chlorido] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254276/ https://www.ncbi.nlm.nih.gov/pubmed/22259334 http://dx.doi.org/10.1107/S1600536811051373 |
work_keys_str_mv | AT xuheng catenapoly8aminoquinolinek2nncadmiumdimthiocyanatok2nsk2sn8aminoquinolinek2nncadmiumdimchlorido AT guochang catenapoly8aminoquinolinek2nncadmiumdimthiocyanatok2nsk2sn8aminoquinolinek2nncadmiumdimchlorido |