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Bis[5-(pyridin-2-yl)pyrazine-2-carbonitrile-κ(2) N (4),N (5)]silver hexafluoridophosphate
In the mononuclear title complex, [Ag(C(10)H(6)N(4))(2)]PF(6), two κ(2) N,N′-chelating 5-(pyridin-2-yl)pyrazine-2-carbonitrile ligands surround the Ag(I) atom, forming a distorted N(4) tetrahedral coordination geometry. The mononuclear units are interconnected through π–π interactions [centroid–c...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254278/ https://www.ncbi.nlm.nih.gov/pubmed/22259349 http://dx.doi.org/10.1107/S1600536811051403 |
Sumario: | In the mononuclear title complex, [Ag(C(10)H(6)N(4))(2)]PF(6), two κ(2) N,N′-chelating 5-(pyridin-2-yl)pyrazine-2-carbonitrile ligands surround the Ag(I) atom, forming a distorted N(4) tetrahedral coordination geometry. The mononuclear units are interconnected through π–π interactions [centroid–centroid distances = 3.801 (2) and 3.979 (3) Å] and the hexafluoridophosphate anions are embedded within the interstices. C N⋯π interactions [N⋯centroid = 3.519 (2) Å] and C—H.⋯N hydrogen-bonding interactions also occur. |
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