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Bis[5-(pyridin-2-yl)pyrazine-2-carbo­nitrile-κ(2) N (4),N (5)]silver hexa­fluorido­phosphate

In the mononuclear title complex, [Ag(C(10)H(6)N(4))(2)]PF(6), two κ(2) N,N′-chelating 5-(pyridin-2-yl)pyrazine-2-carbonitrile ligands surround the Ag(I) atom, forming a distorted N(4) tetra­hedral coordination geometry. The mononuclear units are inter­connected through π–π inter­actions [centroid–c...

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Detalles Bibliográficos
Autor principal: Wang, Zi Jia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254278/
https://www.ncbi.nlm.nih.gov/pubmed/22259349
http://dx.doi.org/10.1107/S1600536811051403
Descripción
Sumario:In the mononuclear title complex, [Ag(C(10)H(6)N(4))(2)]PF(6), two κ(2) N,N′-chelating 5-(pyridin-2-yl)pyrazine-2-carbonitrile ligands surround the Ag(I) atom, forming a distorted N(4) tetra­hedral coordination geometry. The mononuclear units are inter­connected through π–π inter­actions [centroid–centroid distances = 3.801 (2) and 3.979 (3) Å] and the hexa­fluoridophosphate anions are embedded within the inter­stices. C N⋯π inter­actions [N⋯centroid = 3.519 (2) Å] and C—H.⋯N hydrogen-bonding inter­actions also occur.