Tetra­kis(1-allyl-1H-imidazole-κN (3))bis­(thio­cyanato-κN)manganese(II)

The structure of the title compound, [Mn(NCS)(2)(C(6)H(8)N(2))(4)], consists of isolated mol­ecules of [Mn(NCS)(2)(Aim)(4)] (Aim = 1-allyl­imidazole), which contain a compressed octa­hedral MnN(6) chromophore (site symmetry [Image: see text]). The NCS(−) anions are trans and four N atoms from the Ai...

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Detalles Bibliográficos
Autores principales: Zhao, Juan, Jin, Yan-Ling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254281/
https://www.ncbi.nlm.nih.gov/pubmed/22259383
http://dx.doi.org/10.1107/S1600536811051282
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author Zhao, Juan
Jin, Yan-Ling
author_facet Zhao, Juan
Jin, Yan-Ling
author_sort Zhao, Juan
collection PubMed
description The structure of the title compound, [Mn(NCS)(2)(C(6)H(8)N(2))(4)], consists of isolated mol­ecules of [Mn(NCS)(2)(Aim)(4)] (Aim = 1-allyl­imidazole), which contain a compressed octa­hedral MnN(6) chromophore (site symmetry [Image: see text]). The NCS(−) anions are trans and four N atoms from the Aim ligands define the equatorial plane. The mean Mn—N(Aim) and Mn—N(NCS) distances are 2.270 and 2.229 Å, respectively. Weak C—H⋯N inter­actions contribute to the crystal packing stability.
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spelling pubmed-32542812012-01-18 Tetra­kis(1-allyl-1H-imidazole-κN (3))bis­(thio­cyanato-κN)manganese(II) Zhao, Juan Jin, Yan-Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Mn(NCS)(2)(C(6)H(8)N(2))(4)], consists of isolated mol­ecules of [Mn(NCS)(2)(Aim)(4)] (Aim = 1-allyl­imidazole), which contain a compressed octa­hedral MnN(6) chromophore (site symmetry [Image: see text]). The NCS(−) anions are trans and four N atoms from the Aim ligands define the equatorial plane. The mean Mn—N(Aim) and Mn—N(NCS) distances are 2.270 and 2.229 Å, respectively. Weak C—H⋯N inter­actions contribute to the crystal packing stability. International Union of Crystallography 2011-12-03 /pmc/articles/PMC3254281/ /pubmed/22259383 http://dx.doi.org/10.1107/S1600536811051282 Text en © Zhao and Jin 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Juan
Jin, Yan-Ling
Tetra­kis(1-allyl-1H-imidazole-κN (3))bis­(thio­cyanato-κN)manganese(II)
title Tetra­kis(1-allyl-1H-imidazole-κN (3))bis­(thio­cyanato-κN)manganese(II)
title_full Tetra­kis(1-allyl-1H-imidazole-κN (3))bis­(thio­cyanato-κN)manganese(II)
title_fullStr Tetra­kis(1-allyl-1H-imidazole-κN (3))bis­(thio­cyanato-κN)manganese(II)
title_full_unstemmed Tetra­kis(1-allyl-1H-imidazole-κN (3))bis­(thio­cyanato-κN)manganese(II)
title_short Tetra­kis(1-allyl-1H-imidazole-κN (3))bis­(thio­cyanato-κN)manganese(II)
title_sort tetra­kis(1-allyl-1h-imidazole-κn (3))bis­(thio­cyanato-κn)manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254281/
https://www.ncbi.nlm.nih.gov/pubmed/22259383
http://dx.doi.org/10.1107/S1600536811051282
work_keys_str_mv AT zhaojuan tetrakis1allyl1himidazolekn3bisthiocyanatoknmanganeseii
AT jinyanling tetrakis1allyl1himidazolekn3bisthiocyanatoknmanganeseii

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