5′,11′-Dihydro­dispiro­[cyclo­hexane-1,6′-indolo[3,2-b]carbazole-12′,1′′-cyclo­hexa­ne]

The title compound, C(28)H(30)N(2), is a symmetrical 2:2 product from the condensation of indole and cyclo­hexa­none. It is the only reported 5,11-dihydro­indolo[3,2-b]carbazole compound in which the spiro atoms are quaternary C atoms. Crystals were grown by vapor diffusion in a three-zone electric...

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Detalles Bibliográficos
Autores principales: Guzei, Ilia A., Spencer, Lara C., Codner, Eric, Boehm, Joshua M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254282/
https://www.ncbi.nlm.nih.gov/pubmed/22259386
http://dx.doi.org/10.1107/S1600536811051208
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author Guzei, Ilia A.
Spencer, Lara C.
Codner, Eric
Boehm, Joshua M.
author_facet Guzei, Ilia A.
Spencer, Lara C.
Codner, Eric
Boehm, Joshua M.
author_sort Guzei, Ilia A.
collection PubMed
description The title compound, C(28)H(30)N(2), is a symmetrical 2:2 product from the condensation of indole and cyclo­hexa­none. It is the only reported 5,11-dihydro­indolo[3,2-b]carbazole compound in which the spiro atoms are quaternary C atoms. Crystals were grown by vapor diffusion in a three-zone electric furnace. The mol­ecule resides on a crystallographic inversion center. The cyclo­hexyl rings are in a slightly distorted chair conformation, whereas the indole units and the spiro-carbons are coplanar within 0.014 Å.
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spelling pubmed-32542822012-01-18 5′,11′-Dihydro­dispiro­[cyclo­hexane-1,6′-indolo[3,2-b]carbazole-12′,1′′-cyclo­hexa­ne] Guzei, Ilia A. Spencer, Lara C. Codner, Eric Boehm, Joshua M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(28)H(30)N(2), is a symmetrical 2:2 product from the condensation of indole and cyclo­hexa­none. It is the only reported 5,11-dihydro­indolo[3,2-b]carbazole compound in which the spiro atoms are quaternary C atoms. Crystals were grown by vapor diffusion in a three-zone electric furnace. The mol­ecule resides on a crystallographic inversion center. The cyclo­hexyl rings are in a slightly distorted chair conformation, whereas the indole units and the spiro-carbons are coplanar within 0.014 Å. International Union of Crystallography 2011-12-03 /pmc/articles/PMC3254282/ /pubmed/22259386 http://dx.doi.org/10.1107/S1600536811051208 Text en © Guzei et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Guzei, Ilia A.
Spencer, Lara C.
Codner, Eric
Boehm, Joshua M.
5′,11′-Dihydro­dispiro­[cyclo­hexane-1,6′-indolo[3,2-b]carbazole-12′,1′′-cyclo­hexa­ne]
title 5′,11′-Dihydro­dispiro­[cyclo­hexane-1,6′-indolo[3,2-b]carbazole-12′,1′′-cyclo­hexa­ne]
title_full 5′,11′-Dihydro­dispiro­[cyclo­hexane-1,6′-indolo[3,2-b]carbazole-12′,1′′-cyclo­hexa­ne]
title_fullStr 5′,11′-Dihydro­dispiro­[cyclo­hexane-1,6′-indolo[3,2-b]carbazole-12′,1′′-cyclo­hexa­ne]
title_full_unstemmed 5′,11′-Dihydro­dispiro­[cyclo­hexane-1,6′-indolo[3,2-b]carbazole-12′,1′′-cyclo­hexa­ne]
title_short 5′,11′-Dihydro­dispiro­[cyclo­hexane-1,6′-indolo[3,2-b]carbazole-12′,1′′-cyclo­hexa­ne]
title_sort 5′,11′-dihydro­dispiro­[cyclo­hexane-1,6′-indolo[3,2-b]carbazole-12′,1′′-cyclo­hexa­ne]
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254282/
https://www.ncbi.nlm.nih.gov/pubmed/22259386
http://dx.doi.org/10.1107/S1600536811051208
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