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(3-{[N-(5-Chloro-2-hydroxyphenyl)oxamoyl]amino}propyl)dimethylazanium perchlorate
In the title compound, C(13)H(19)ClN(3)O(3) (+)·ClO(4) (−), the 3-(dimethylammonio)propyl group of the cation is disordered over two sets of sites with occupancies 0.772 (6) and 0.228 (6). The cations are joined by pairs of N—H⋯O hydrogen bonds into centrosymmetric dimers and these dimers are as...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254288/ https://www.ncbi.nlm.nih.gov/pubmed/22259579 http://dx.doi.org/10.1107/S1600536811050653 |
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author | Yue, Xi-Teng Li, Xiao-Wen Wu, Zhi-Yong |
author_facet | Yue, Xi-Teng Li, Xiao-Wen Wu, Zhi-Yong |
author_sort | Yue, Xi-Teng |
collection | PubMed |
description | In the title compound, C(13)H(19)ClN(3)O(3) (+)·ClO(4) (−), the 3-(dimethylammonio)propyl group of the cation is disordered over two sets of sites with occupancies 0.772 (6) and 0.228 (6). The cations are joined by pairs of N—H⋯O hydrogen bonds into centrosymmetric dimers and these dimers are assembled into chains along the a-axis direction, also through N—H⋯O hydrogen bonds. The perchlorate anions are linked to the hydroxy groups of the cations by O—H⋯O hydrogen bonds. The positively charged ammonium groups and the anions give rise to folded layers parallel to the ab plane. |
format | Online Article Text |
id | pubmed-3254288 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32542882012-01-18 (3-{[N-(5-Chloro-2-hydroxyphenyl)oxamoyl]amino}propyl)dimethylazanium perchlorate Yue, Xi-Teng Li, Xiao-Wen Wu, Zhi-Yong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(19)ClN(3)O(3) (+)·ClO(4) (−), the 3-(dimethylammonio)propyl group of the cation is disordered over two sets of sites with occupancies 0.772 (6) and 0.228 (6). The cations are joined by pairs of N—H⋯O hydrogen bonds into centrosymmetric dimers and these dimers are assembled into chains along the a-axis direction, also through N—H⋯O hydrogen bonds. The perchlorate anions are linked to the hydroxy groups of the cations by O—H⋯O hydrogen bonds. The positively charged ammonium groups and the anions give rise to folded layers parallel to the ab plane. International Union of Crystallography 2011-12-03 /pmc/articles/PMC3254288/ /pubmed/22259579 http://dx.doi.org/10.1107/S1600536811050653 Text en © Yue et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Yue, Xi-Teng Li, Xiao-Wen Wu, Zhi-Yong (3-{[N-(5-Chloro-2-hydroxyphenyl)oxamoyl]amino}propyl)dimethylazanium perchlorate |
title | (3-{[N-(5-Chloro-2-hydroxyphenyl)oxamoyl]amino}propyl)dimethylazanium perchlorate |
title_full | (3-{[N-(5-Chloro-2-hydroxyphenyl)oxamoyl]amino}propyl)dimethylazanium perchlorate |
title_fullStr | (3-{[N-(5-Chloro-2-hydroxyphenyl)oxamoyl]amino}propyl)dimethylazanium perchlorate |
title_full_unstemmed | (3-{[N-(5-Chloro-2-hydroxyphenyl)oxamoyl]amino}propyl)dimethylazanium perchlorate |
title_short | (3-{[N-(5-Chloro-2-hydroxyphenyl)oxamoyl]amino}propyl)dimethylazanium perchlorate |
title_sort | (3-{[n-(5-chloro-2-hydroxyphenyl)oxamoyl]amino}propyl)dimethylazanium perchlorate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254288/ https://www.ncbi.nlm.nih.gov/pubmed/22259579 http://dx.doi.org/10.1107/S1600536811050653 |
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