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(E)-3-(2-Nitro­phen­yl)-1-{1-phenyl­sulfonyl-2-[(phenyl­sulfon­yl)meth­yl]-1H-indol-3-yl}prop-2-en-1-one

In the title compound, C(30)H(22)N(2)O(7)S(2), the configuration about the propene C=C bond is E. The indole unit is essentially planar, with a maximum deviation of 0.031 (3) Å. The dihedral angle between the planes of the phenyl rings of the two phenyl­sulfonyl groups is 80.95 (19)°. The central pr...

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Autores principales: Karthikeyan, S., Sethusankar, K., Rajeswaran, Ganesan Gobi, Mohanakrishnan, Arasambattu K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254289/
https://www.ncbi.nlm.nih.gov/pubmed/22259588
http://dx.doi.org/10.1107/S1600536811051026
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author Karthikeyan, S.
Sethusankar, K.
Rajeswaran, Ganesan Gobi
Mohanakrishnan, Arasambattu K.
author_facet Karthikeyan, S.
Sethusankar, K.
Rajeswaran, Ganesan Gobi
Mohanakrishnan, Arasambattu K.
author_sort Karthikeyan, S.
collection PubMed
description In the title compound, C(30)H(22)N(2)O(7)S(2), the configuration about the propene C=C bond is E. The indole unit is essentially planar, with a maximum deviation of 0.031 (3) Å. The dihedral angle between the planes of the phenyl rings of the two phenyl­sulfonyl groups is 80.95 (19)°. The central prop-2-ene-1-one group is oriented at a dihedral angle of 44.26 (11)° with respect to the nitro­phenyl ring and at 39.24 (8)° with respect to the indole unit. The S atoms are in a distorted tetra­hedral configuration. In the crystal, mol­ecules are linked into centrosymmetric dimers via pairs of C—H⋯O hydrogen bonds with an R (2) (2)(24) graph-set motif. The crystal structure is stabilized by further C—H⋯O inter­actions. Short intra­molecular C—H⋯O contacts result in several S(6) rings.
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spelling pubmed-32542892012-01-18 (E)-3-(2-Nitro­phen­yl)-1-{1-phenyl­sulfonyl-2-[(phenyl­sulfon­yl)meth­yl]-1H-indol-3-yl}prop-2-en-1-one Karthikeyan, S. Sethusankar, K. Rajeswaran, Ganesan Gobi Mohanakrishnan, Arasambattu K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(30)H(22)N(2)O(7)S(2), the configuration about the propene C=C bond is E. The indole unit is essentially planar, with a maximum deviation of 0.031 (3) Å. The dihedral angle between the planes of the phenyl rings of the two phenyl­sulfonyl groups is 80.95 (19)°. The central prop-2-ene-1-one group is oriented at a dihedral angle of 44.26 (11)° with respect to the nitro­phenyl ring and at 39.24 (8)° with respect to the indole unit. The S atoms are in a distorted tetra­hedral configuration. In the crystal, mol­ecules are linked into centrosymmetric dimers via pairs of C—H⋯O hydrogen bonds with an R (2) (2)(24) graph-set motif. The crystal structure is stabilized by further C—H⋯O inter­actions. Short intra­molecular C—H⋯O contacts result in several S(6) rings. International Union of Crystallography 2011-12-03 /pmc/articles/PMC3254289/ /pubmed/22259588 http://dx.doi.org/10.1107/S1600536811051026 Text en © Karthikeyan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Karthikeyan, S.
Sethusankar, K.
Rajeswaran, Ganesan Gobi
Mohanakrishnan, Arasambattu K.
(E)-3-(2-Nitro­phen­yl)-1-{1-phenyl­sulfonyl-2-[(phenyl­sulfon­yl)meth­yl]-1H-indol-3-yl}prop-2-en-1-one
title (E)-3-(2-Nitro­phen­yl)-1-{1-phenyl­sulfonyl-2-[(phenyl­sulfon­yl)meth­yl]-1H-indol-3-yl}prop-2-en-1-one
title_full (E)-3-(2-Nitro­phen­yl)-1-{1-phenyl­sulfonyl-2-[(phenyl­sulfon­yl)meth­yl]-1H-indol-3-yl}prop-2-en-1-one
title_fullStr (E)-3-(2-Nitro­phen­yl)-1-{1-phenyl­sulfonyl-2-[(phenyl­sulfon­yl)meth­yl]-1H-indol-3-yl}prop-2-en-1-one
title_full_unstemmed (E)-3-(2-Nitro­phen­yl)-1-{1-phenyl­sulfonyl-2-[(phenyl­sulfon­yl)meth­yl]-1H-indol-3-yl}prop-2-en-1-one
title_short (E)-3-(2-Nitro­phen­yl)-1-{1-phenyl­sulfonyl-2-[(phenyl­sulfon­yl)meth­yl]-1H-indol-3-yl}prop-2-en-1-one
title_sort (e)-3-(2-nitro­phen­yl)-1-{1-phenyl­sulfonyl-2-[(phenyl­sulfon­yl)meth­yl]-1h-indol-3-yl}prop-2-en-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254289/
https://www.ncbi.nlm.nih.gov/pubmed/22259588
http://dx.doi.org/10.1107/S1600536811051026
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