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Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]nickel(II) decahydrate
In the title compound, [Ni(C(9)H(6)N(3)O(2))(2)(H(2)O)(4)]·10H(2)O, the Ni(II) ion lies on a twofold rotation axis and displays a slightly distorted octahedral geometry defined by two N atoms from two monodentate 4-(1,2,4-triazol-4-yl)benzoate ligands and four water molecules, two of which also li...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254290/ https://www.ncbi.nlm.nih.gov/pubmed/22259318 http://dx.doi.org/10.1107/S1600536811051063 |
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author | Sun, Weixuan Yu, Yaqin Wang, Guanjun Wu, Xiaohui |
author_facet | Sun, Weixuan Yu, Yaqin Wang, Guanjun Wu, Xiaohui |
author_sort | Sun, Weixuan |
collection | PubMed |
description | In the title compound, [Ni(C(9)H(6)N(3)O(2))(2)(H(2)O)(4)]·10H(2)O, the Ni(II) ion lies on a twofold rotation axis and displays a slightly distorted octahedral geometry defined by two N atoms from two monodentate 4-(1,2,4-triazol-4-yl)benzoate ligands and four water molecules, two of which also lie on the twofold rotation axis. In the crystal, the complex molecules and uncoordinated water molecules are linked via intermolecular O—H⋯N and O—H⋯O hydrogen bonds, forming a three-dimensional supramolecular network. π–π interactions between the benzene rings provide additional stability of the crystal packing [centroid–centroid distance = 3.792 (2) Å]. |
format | Online Article Text |
id | pubmed-3254290 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32542902012-01-18 Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]nickel(II) decahydrate Sun, Weixuan Yu, Yaqin Wang, Guanjun Wu, Xiaohui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(9)H(6)N(3)O(2))(2)(H(2)O)(4)]·10H(2)O, the Ni(II) ion lies on a twofold rotation axis and displays a slightly distorted octahedral geometry defined by two N atoms from two monodentate 4-(1,2,4-triazol-4-yl)benzoate ligands and four water molecules, two of which also lie on the twofold rotation axis. In the crystal, the complex molecules and uncoordinated water molecules are linked via intermolecular O—H⋯N and O—H⋯O hydrogen bonds, forming a three-dimensional supramolecular network. π–π interactions between the benzene rings provide additional stability of the crystal packing [centroid–centroid distance = 3.792 (2) Å]. International Union of Crystallography 2011-12-03 /pmc/articles/PMC3254290/ /pubmed/22259318 http://dx.doi.org/10.1107/S1600536811051063 Text en © Sun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sun, Weixuan Yu, Yaqin Wang, Guanjun Wu, Xiaohui Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]nickel(II) decahydrate |
title | Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN
(1)]nickel(II) decahydrate |
title_full | Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN
(1)]nickel(II) decahydrate |
title_fullStr | Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN
(1)]nickel(II) decahydrate |
title_full_unstemmed | Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN
(1)]nickel(II) decahydrate |
title_short | Tetraaquabis[4-(4H-1,2,4-triazol-4-yl)benzoato-κN
(1)]nickel(II) decahydrate |
title_sort | tetraaquabis[4-(4h-1,2,4-triazol-4-yl)benzoato-κn
(1)]nickel(ii) decahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254290/ https://www.ncbi.nlm.nih.gov/pubmed/22259318 http://dx.doi.org/10.1107/S1600536811051063 |
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