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Tetra­aqua­bis­[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]nickel(II) deca­hydrate

In the title compound, [Ni(C(9)H(6)N(3)O(2))(2)(H(2)O)(4)]·10H(2)O, the Ni(II) ion lies on a twofold rotation axis and displays a slightly distorted octa­hedral geometry defined by two N atoms from two monodentate 4-(1,2,4-triazol-4-yl)benzoate ligands and four water mol­ecules, two of which also li...

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Detalles Bibliográficos
Autores principales: Sun, Weixuan, Yu, Yaqin, Wang, Guanjun, Wu, Xiaohui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254290/
https://www.ncbi.nlm.nih.gov/pubmed/22259318
http://dx.doi.org/10.1107/S1600536811051063
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author Sun, Weixuan
Yu, Yaqin
Wang, Guanjun
Wu, Xiaohui
author_facet Sun, Weixuan
Yu, Yaqin
Wang, Guanjun
Wu, Xiaohui
author_sort Sun, Weixuan
collection PubMed
description In the title compound, [Ni(C(9)H(6)N(3)O(2))(2)(H(2)O)(4)]·10H(2)O, the Ni(II) ion lies on a twofold rotation axis and displays a slightly distorted octa­hedral geometry defined by two N atoms from two monodentate 4-(1,2,4-triazol-4-yl)benzoate ligands and four water mol­ecules, two of which also lie on the twofold rotation axis. In the crystal, the complex mol­ecules and uncoordinated water mol­ecules are linked via inter­molecular O—H⋯N and O—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular network. π–π inter­actions between the benzene rings provide additional stability of the crystal packing [centroid–centroid distance = 3.792 (2) Å].
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spelling pubmed-32542902012-01-18 Tetra­aqua­bis­[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]nickel(II) deca­hydrate Sun, Weixuan Yu, Yaqin Wang, Guanjun Wu, Xiaohui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(9)H(6)N(3)O(2))(2)(H(2)O)(4)]·10H(2)O, the Ni(II) ion lies on a twofold rotation axis and displays a slightly distorted octa­hedral geometry defined by two N atoms from two monodentate 4-(1,2,4-triazol-4-yl)benzoate ligands and four water mol­ecules, two of which also lie on the twofold rotation axis. In the crystal, the complex mol­ecules and uncoordinated water mol­ecules are linked via inter­molecular O—H⋯N and O—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular network. π–π inter­actions between the benzene rings provide additional stability of the crystal packing [centroid–centroid distance = 3.792 (2) Å]. International Union of Crystallography 2011-12-03 /pmc/articles/PMC3254290/ /pubmed/22259318 http://dx.doi.org/10.1107/S1600536811051063 Text en © Sun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sun, Weixuan
Yu, Yaqin
Wang, Guanjun
Wu, Xiaohui
Tetra­aqua­bis­[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]nickel(II) deca­hydrate
title Tetra­aqua­bis­[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]nickel(II) deca­hydrate
title_full Tetra­aqua­bis­[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]nickel(II) deca­hydrate
title_fullStr Tetra­aqua­bis­[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]nickel(II) deca­hydrate
title_full_unstemmed Tetra­aqua­bis­[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]nickel(II) deca­hydrate
title_short Tetra­aqua­bis­[4-(4H-1,2,4-triazol-4-yl)benzoato-κN (1)]nickel(II) deca­hydrate
title_sort tetra­aqua­bis­[4-(4h-1,2,4-triazol-4-yl)benzoato-κn (1)]nickel(ii) deca­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254290/
https://www.ncbi.nlm.nih.gov/pubmed/22259318
http://dx.doi.org/10.1107/S1600536811051063
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