Bis[2-(1-imino­eth­yl)phenolato-κ(2) N,O]nickel(II)

There are one and a half independent mol­ecules in the asymmetric unit of the title compound, [Ni(C(8)H(8)NO)(2)], one of which is situated on an inversion center. In both mol­ecules, the Ni(II) ion is coordinated by two O and two N atoms from two Schiff base ligands in an approximate square-planar...

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Autor principal: Wang, Ning
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254291/
https://www.ncbi.nlm.nih.gov/pubmed/22259319
http://dx.doi.org/10.1107/S1600536811051476
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author Wang, Ning
author_facet Wang, Ning
author_sort Wang, Ning
collection PubMed
description There are one and a half independent mol­ecules in the asymmetric unit of the title compound, [Ni(C(8)H(8)NO)(2)], one of which is situated on an inversion center. In both mol­ecules, the Ni(II) ion is coordinated by two O and two N atoms from two Schiff base ligands in an approximate square-planar geometry. Inter­molecular N—H⋯O hydrogen bonds link three mol­ecules into centrosymmetric trimer. The crystal packing exhibits weak inter­molecular C—H⋯O hydrogen bonds and voids of 37 Å(3).
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spelling pubmed-32542912012-01-18 Bis[2-(1-imino­eth­yl)phenolato-κ(2) N,O]nickel(II) Wang, Ning Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers There are one and a half independent mol­ecules in the asymmetric unit of the title compound, [Ni(C(8)H(8)NO)(2)], one of which is situated on an inversion center. In both mol­ecules, the Ni(II) ion is coordinated by two O and two N atoms from two Schiff base ligands in an approximate square-planar geometry. Inter­molecular N—H⋯O hydrogen bonds link three mol­ecules into centrosymmetric trimer. The crystal packing exhibits weak inter­molecular C—H⋯O hydrogen bonds and voids of 37 Å(3). International Union of Crystallography 2011-12-03 /pmc/articles/PMC3254291/ /pubmed/22259319 http://dx.doi.org/10.1107/S1600536811051476 Text en © Ning Wang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Ning
Bis[2-(1-imino­eth­yl)phenolato-κ(2) N,O]nickel(II)
title Bis[2-(1-imino­eth­yl)phenolato-κ(2) N,O]nickel(II)
title_full Bis[2-(1-imino­eth­yl)phenolato-κ(2) N,O]nickel(II)
title_fullStr Bis[2-(1-imino­eth­yl)phenolato-κ(2) N,O]nickel(II)
title_full_unstemmed Bis[2-(1-imino­eth­yl)phenolato-κ(2) N,O]nickel(II)
title_short Bis[2-(1-imino­eth­yl)phenolato-κ(2) N,O]nickel(II)
title_sort bis[2-(1-imino­eth­yl)phenolato-κ(2) n,o]nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254291/
https://www.ncbi.nlm.nih.gov/pubmed/22259319
http://dx.doi.org/10.1107/S1600536811051476
work_keys_str_mv AT wangning bis21iminoethylphenolatok2nonickelii

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