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Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ(3) S,S′:S′;2:1κ(3) S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ(2) S,S′)cadmium]
In the centrosymmetric title compound, [Cd(2)(C(13)H(12)NOS(2))(4)], pairs of dithiocarbamate ligands exhibit different structural functions. Each of the terminal ligands is bidentately coordinated to one Cd(II) atom and forms a planar four-membered CS(2)Cd chelate ring, whereas pairs of the triden...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254292/ https://www.ncbi.nlm.nih.gov/pubmed/22259320 http://dx.doi.org/10.1107/S1600536811051348 |
| _version_ | 1782220826238517248 |
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| author | Kant, Rajni Gupta, Vivek K. Kapoor, Kamini Valarmathi, P. Thirumaran, S. |
| author_facet | Kant, Rajni Gupta, Vivek K. Kapoor, Kamini Valarmathi, P. Thirumaran, S. |
| author_sort | Kant, Rajni |
| collection | PubMed |
| description | In the centrosymmetric title compound, [Cd(2)(C(13)H(12)NOS(2))(4)], pairs of dithiocarbamate ligands exhibit different structural functions. Each of the terminal ligands is bidentately coordinated to one Cd(II) atom and forms a planar four-membered CS(2)Cd chelate ring, whereas pairs of the tridentate bridging ligands link two neighbouring Cd(II) atoms, forming extended eight-membered C(2)S(4)Cd(2) tricyclic units whose geometry can be approximated by a chair conformation. The coordination polyhedron of the Cd(II) atoms is a distorted square-pyramid. The five-membered furan ring and the benzene ring are disordered over two sets of sites with an occupancy ratio of 0.62 (8):0.38 (8). |
| format | Online Article Text |
| id | pubmed-3254292 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32542922012-01-18 Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ(3) S,S′:S′;2:1κ(3) S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ(2) S,S′)cadmium] Kant, Rajni Gupta, Vivek K. Kapoor, Kamini Valarmathi, P. Thirumaran, S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title compound, [Cd(2)(C(13)H(12)NOS(2))(4)], pairs of dithiocarbamate ligands exhibit different structural functions. Each of the terminal ligands is bidentately coordinated to one Cd(II) atom and forms a planar four-membered CS(2)Cd chelate ring, whereas pairs of the tridentate bridging ligands link two neighbouring Cd(II) atoms, forming extended eight-membered C(2)S(4)Cd(2) tricyclic units whose geometry can be approximated by a chair conformation. The coordination polyhedron of the Cd(II) atoms is a distorted square-pyramid. The five-membered furan ring and the benzene ring are disordered over two sets of sites with an occupancy ratio of 0.62 (8):0.38 (8). International Union of Crystallography 2011-12-03 /pmc/articles/PMC3254292/ /pubmed/22259320 http://dx.doi.org/10.1107/S1600536811051348 Text en © Kant et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kant, Rajni Gupta, Vivek K. Kapoor, Kamini Valarmathi, P. Thirumaran, S. Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ(3) S,S′:S′;2:1κ(3) S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ(2) S,S′)cadmium] |
| title | Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ(3)
S,S′:S′;2:1κ(3)
S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ(2)
S,S′)cadmium] |
| title_full | Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ(3)
S,S′:S′;2:1κ(3)
S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ(2)
S,S′)cadmium] |
| title_fullStr | Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ(3)
S,S′:S′;2:1κ(3)
S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ(2)
S,S′)cadmium] |
| title_full_unstemmed | Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ(3)
S,S′:S′;2:1κ(3)
S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ(2)
S,S′)cadmium] |
| title_short | Bis(μ-N-benzyl-N-furfuryldithiocarbamato)-1:2κ(3)
S,S′:S′;2:1κ(3)
S,S′:S′-bis[(N-benzyl-N-furfuryldithiocarbamato-κ(2)
S,S′)cadmium] |
| title_sort | bis(μ-n-benzyl-n-furfuryldithiocarbamato)-1:2κ(3)
s,s′:s′;2:1κ(3)
s,s′:s′-bis[(n-benzyl-n-furfuryldithiocarbamato-κ(2)
s,s′)cadmium] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254292/ https://www.ncbi.nlm.nih.gov/pubmed/22259320 http://dx.doi.org/10.1107/S1600536811051348 |
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