trans-Dichloridobis[dicyclo­hex­yl(4-isopropyl­phen­yl)phosphane-κP]platinum(II) acetone monosolvate

The title compound, [PtCl(2)(C(21)H(33)P)(2)]·C(3)H(6)O, crystallizes with an accompanying acetone solvent mol­ecule. The metal atom shows a distorted square-planar coordination environment, with a P—Pt—P angle of 172.41 (3)° as the most prominent feature. Both isopropyl fragments were treated as di...

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Detalles Bibliográficos
Autores principales: Vuba, Bubele, Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254293/
https://www.ncbi.nlm.nih.gov/pubmed/22259321
http://dx.doi.org/10.1107/S1600536811051841
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author Vuba, Bubele
Muller, Alfred
author_facet Vuba, Bubele
Muller, Alfred
author_sort Vuba, Bubele
collection PubMed
description The title compound, [PtCl(2)(C(21)H(33)P)(2)]·C(3)H(6)O, crystallizes with an accompanying acetone solvent mol­ecule. The metal atom shows a distorted square-planar coordination environment, with a P—Pt—P angle of 172.41 (3)° as the most prominent feature. Both isopropyl fragments were treated as disordered over two conformations with occupancy ratios of 0.55 (2):0.45 (2) and 0.58 (2):0.42 (2). The solvent mol­ecule was also disordered over two orientations in a 1:1 ratio. The crystal studied was a non-merohedral twin with a twin component of 32.4%.
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spelling pubmed-32542932012-01-18 trans-Dichloridobis[dicyclo­hex­yl(4-isopropyl­phen­yl)phosphane-κP]platinum(II) acetone monosolvate Vuba, Bubele Muller, Alfred Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [PtCl(2)(C(21)H(33)P)(2)]·C(3)H(6)O, crystallizes with an accompanying acetone solvent mol­ecule. The metal atom shows a distorted square-planar coordination environment, with a P—Pt—P angle of 172.41 (3)° as the most prominent feature. Both isopropyl fragments were treated as disordered over two conformations with occupancy ratios of 0.55 (2):0.45 (2) and 0.58 (2):0.42 (2). The solvent mol­ecule was also disordered over two orientations in a 1:1 ratio. The crystal studied was a non-merohedral twin with a twin component of 32.4%. International Union of Crystallography 2011-12-07 /pmc/articles/PMC3254293/ /pubmed/22259321 http://dx.doi.org/10.1107/S1600536811051841 Text en © Vuba and Muller 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Vuba, Bubele
Muller, Alfred
trans-Dichloridobis[dicyclo­hex­yl(4-isopropyl­phen­yl)phosphane-κP]platinum(II) acetone monosolvate
title trans-Dichloridobis[dicyclo­hex­yl(4-isopropyl­phen­yl)phosphane-κP]platinum(II) acetone monosolvate
title_full trans-Dichloridobis[dicyclo­hex­yl(4-isopropyl­phen­yl)phosphane-κP]platinum(II) acetone monosolvate
title_fullStr trans-Dichloridobis[dicyclo­hex­yl(4-isopropyl­phen­yl)phosphane-κP]platinum(II) acetone monosolvate
title_full_unstemmed trans-Dichloridobis[dicyclo­hex­yl(4-isopropyl­phen­yl)phosphane-κP]platinum(II) acetone monosolvate
title_short trans-Dichloridobis[dicyclo­hex­yl(4-isopropyl­phen­yl)phosphane-κP]platinum(II) acetone monosolvate
title_sort trans-dichloridobis[dicyclo­hex­yl(4-isopropyl­phen­yl)phosphane-κp]platinum(ii) acetone monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254293/
https://www.ncbi.nlm.nih.gov/pubmed/22259321
http://dx.doi.org/10.1107/S1600536811051841
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AT mulleralfred transdichloridobisdicyclohexyl4isopropylphenylphosphanekpplatinumiiacetonemonosolvate

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