2-Bromo-1,3-diisopropyl-4,5-dimethyl-1H-imidazol-3-ium dicyanidoargentate

The title structure, (C(11)H(20)BrN(2))[Ag(CN)(2))], is built up from an approximately C (2v)-symmetric imidazolium cation and a nearly linear dicyanidoargentate anion [N—Ag—N = 176.6 (9)° and Ag—C—N = 178.8 (9) and 177.2 (11)°]. These two constituents are linked by a remarkably short inter­action b...

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Autores principales: Mallah, Eyad, Sweidan, Kamal, Abu-Salem, Qutaiba, Abu Dayyih, Wael, Steimann, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254295/
https://www.ncbi.nlm.nih.gov/pubmed/22259323
http://dx.doi.org/10.1107/S1600536811051828
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author Mallah, Eyad
Sweidan, Kamal
Abu-Salem, Qutaiba
Abu Dayyih, Wael
Steimann, Manfred
author_facet Mallah, Eyad
Sweidan, Kamal
Abu-Salem, Qutaiba
Abu Dayyih, Wael
Steimann, Manfred
author_sort Mallah, Eyad
collection PubMed
description The title structure, (C(11)H(20)BrN(2))[Ag(CN)(2))], is built up from an approximately C (2v)-symmetric imidazolium cation and a nearly linear dicyanidoargentate anion [N—Ag—N = 176.6 (9)° and Ag—C—N = 178.8 (9) and 177.2 (11)°]. These two constituents are linked by a remarkably short inter­action between the Br atom of the imidazolium cation [C—Br = 1.85 (3) Å] and one N atom of the cyanidoargentate anion [Br⋯N = 2.96 (2) Å], which is much less than the sum of the van der Waals radii (3.40 Å). The crystal studied was twinned by merohedry.
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spelling pubmed-32542952012-01-18 2-Bromo-1,3-diisopropyl-4,5-dimethyl-1H-imidazol-3-ium dicyanidoargentate Mallah, Eyad Sweidan, Kamal Abu-Salem, Qutaiba Abu Dayyih, Wael Steimann, Manfred Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title structure, (C(11)H(20)BrN(2))[Ag(CN)(2))], is built up from an approximately C (2v)-symmetric imidazolium cation and a nearly linear dicyanidoargentate anion [N—Ag—N = 176.6 (9)° and Ag—C—N = 178.8 (9) and 177.2 (11)°]. These two constituents are linked by a remarkably short inter­action between the Br atom of the imidazolium cation [C—Br = 1.85 (3) Å] and one N atom of the cyanidoargentate anion [Br⋯N = 2.96 (2) Å], which is much less than the sum of the van der Waals radii (3.40 Å). The crystal studied was twinned by merohedry. International Union of Crystallography 2011-12-07 /pmc/articles/PMC3254295/ /pubmed/22259323 http://dx.doi.org/10.1107/S1600536811051828 Text en © Mallah et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mallah, Eyad
Sweidan, Kamal
Abu-Salem, Qutaiba
Abu Dayyih, Wael
Steimann, Manfred
2-Bromo-1,3-diisopropyl-4,5-dimethyl-1H-imidazol-3-ium dicyanidoargentate
title 2-Bromo-1,3-diisopropyl-4,5-dimethyl-1H-imidazol-3-ium dicyanidoargentate
title_full 2-Bromo-1,3-diisopropyl-4,5-dimethyl-1H-imidazol-3-ium dicyanidoargentate
title_fullStr 2-Bromo-1,3-diisopropyl-4,5-dimethyl-1H-imidazol-3-ium dicyanidoargentate
title_full_unstemmed 2-Bromo-1,3-diisopropyl-4,5-dimethyl-1H-imidazol-3-ium dicyanidoargentate
title_short 2-Bromo-1,3-diisopropyl-4,5-dimethyl-1H-imidazol-3-ium dicyanidoargentate
title_sort 2-bromo-1,3-diisopropyl-4,5-dimethyl-1h-imidazol-3-ium dicyanidoargentate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254295/
https://www.ncbi.nlm.nih.gov/pubmed/22259323
http://dx.doi.org/10.1107/S1600536811051828
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