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Bis(μ-di-2-pyridyl disulfide-κ(3) N,S:N′)di-μ(3)-iodido-di-μ(2)-iodido-tetracopper(I)
In the centrosymmetric tetranuclear title compound, [Cu(4)I(4)(C(10)H(8)N(2)S(2))(2)], there are two different Cu(I) atoms with tetrahedral coordination geometries. One is chelated by a pyridine N atom and an S-donor from one di-2-pyridyl disulfide ligand and coordinated by two I atoms, while the...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254296/ https://www.ncbi.nlm.nih.gov/pubmed/22259324 http://dx.doi.org/10.1107/S160053681105152X |
| Sumario: | In the centrosymmetric tetranuclear title compound, [Cu(4)I(4)(C(10)H(8)N(2)S(2))(2)], there are two different Cu(I) atoms with tetrahedral coordination geometries. One is chelated by a pyridine N atom and an S-donor from one di-2-pyridyl disulfide ligand and coordinated by two I atoms, while the second Cu(I) atom is coordinated by a pyridine-N and three I atoms. Iodine bridges between the Cu(I) atoms form a tetranuclear structure. |
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