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Bis(μ-di-2-pyridyl disulfide-κ(3) N,S:N′)di-μ(3)-iodido-di-μ(2)-iodido-tetracopper(I)
In the centrosymmetric tetranuclear title compound, [Cu(4)I(4)(C(10)H(8)N(2)S(2))(2)], there are two different Cu(I) atoms with tetrahedral coordination geometries. One is chelated by a pyridine N atom and an S-donor from one di-2-pyridyl disulfide ligand and coordinated by two I atoms, while the...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254296/ https://www.ncbi.nlm.nih.gov/pubmed/22259324 http://dx.doi.org/10.1107/S160053681105152X |
| _version_ | 1782220827144486912 |
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| author | Wang, Yu-Hong Zhu, Xue-Hua |
| author_facet | Wang, Yu-Hong Zhu, Xue-Hua |
| author_sort | Wang, Yu-Hong |
| collection | PubMed |
| description | In the centrosymmetric tetranuclear title compound, [Cu(4)I(4)(C(10)H(8)N(2)S(2))(2)], there are two different Cu(I) atoms with tetrahedral coordination geometries. One is chelated by a pyridine N atom and an S-donor from one di-2-pyridyl disulfide ligand and coordinated by two I atoms, while the second Cu(I) atom is coordinated by a pyridine-N and three I atoms. Iodine bridges between the Cu(I) atoms form a tetranuclear structure. |
| format | Online Article Text |
| id | pubmed-3254296 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32542962012-01-18 Bis(μ-di-2-pyridyl disulfide-κ(3) N,S:N′)di-μ(3)-iodido-di-μ(2)-iodido-tetracopper(I) Wang, Yu-Hong Zhu, Xue-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric tetranuclear title compound, [Cu(4)I(4)(C(10)H(8)N(2)S(2))(2)], there are two different Cu(I) atoms with tetrahedral coordination geometries. One is chelated by a pyridine N atom and an S-donor from one di-2-pyridyl disulfide ligand and coordinated by two I atoms, while the second Cu(I) atom is coordinated by a pyridine-N and three I atoms. Iodine bridges between the Cu(I) atoms form a tetranuclear structure. International Union of Crystallography 2011-12-07 /pmc/articles/PMC3254296/ /pubmed/22259324 http://dx.doi.org/10.1107/S160053681105152X Text en © Wang and Zhu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Yu-Hong Zhu, Xue-Hua Bis(μ-di-2-pyridyl disulfide-κ(3) N,S:N′)di-μ(3)-iodido-di-μ(2)-iodido-tetracopper(I) |
| title | Bis(μ-di-2-pyridyl disulfide-κ(3)
N,S:N′)di-μ(3)-iodido-di-μ(2)-iodido-tetracopper(I) |
| title_full | Bis(μ-di-2-pyridyl disulfide-κ(3)
N,S:N′)di-μ(3)-iodido-di-μ(2)-iodido-tetracopper(I) |
| title_fullStr | Bis(μ-di-2-pyridyl disulfide-κ(3)
N,S:N′)di-μ(3)-iodido-di-μ(2)-iodido-tetracopper(I) |
| title_full_unstemmed | Bis(μ-di-2-pyridyl disulfide-κ(3)
N,S:N′)di-μ(3)-iodido-di-μ(2)-iodido-tetracopper(I) |
| title_short | Bis(μ-di-2-pyridyl disulfide-κ(3)
N,S:N′)di-μ(3)-iodido-di-μ(2)-iodido-tetracopper(I) |
| title_sort | bis(μ-di-2-pyridyl disulfide-κ(3)
n,s:n′)di-μ(3)-iodido-di-μ(2)-iodido-tetracopper(i) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254296/ https://www.ncbi.nlm.nih.gov/pubmed/22259324 http://dx.doi.org/10.1107/S160053681105152X |
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