catena-Poly[1-[(2-fluoro­benzyl­idene)amino]­quinolinium [plumbate(II)-tri-μ-iodido]]

The title complex, {(C(16)H(12)FN(2))[PbI(3)]}(n), consists of 1-[(2-fluoro­benzyl­idene)amino]­quinolinium cations and a polymeric PbI(3) (−) anion formed by face-sharing PbI(6) octa­hedra. These octa­hedra form straight and regular infinite chains along the b axis. In the asymmetric unit, one cati...

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Detalles Bibliográficos
Autor principal: Zhao, Hai-Rong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254297/
https://www.ncbi.nlm.nih.gov/pubmed/22259325
http://dx.doi.org/10.1107/S1600536811051853
Descripción
Sumario:The title complex, {(C(16)H(12)FN(2))[PbI(3)]}(n), consists of 1-[(2-fluoro­benzyl­idene)amino]­quinolinium cations and a polymeric PbI(3) (−) anion formed by face-sharing PbI(6) octa­hedra. These octa­hedra form straight and regular infinite chains along the b axis. In the asymmetric unit, one cation and one anionic [PbI(3)](−) fragment are observed in general positions. Polymeric chains are produced by the glide plane perpendicular to the a axis.

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