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catena-Poly[1-[(2-fluorobenzylidene)amino]quinolinium [plumbate(II)-tri-μ-iodido]]
The title complex, {(C(16)H(12)FN(2))[PbI(3)]}(n), consists of 1-[(2-fluorobenzylidene)amino]quinolinium cations and a polymeric PbI(3) (−) anion formed by face-sharing PbI(6) octahedra. These octahedra form straight and regular infinite chains along the b axis. In the asymmetric unit, one cati...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254297/ https://www.ncbi.nlm.nih.gov/pubmed/22259325 http://dx.doi.org/10.1107/S1600536811051853 |
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author | Zhao, Hai-Rong |
author_facet | Zhao, Hai-Rong |
author_sort | Zhao, Hai-Rong |
collection | PubMed |
description | The title complex, {(C(16)H(12)FN(2))[PbI(3)]}(n), consists of 1-[(2-fluorobenzylidene)amino]quinolinium cations and a polymeric PbI(3) (−) anion formed by face-sharing PbI(6) octahedra. These octahedra form straight and regular infinite chains along the b axis. In the asymmetric unit, one cation and one anionic [PbI(3)](−) fragment are observed in general positions. Polymeric chains are produced by the glide plane perpendicular to the a axis. |
format | Online Article Text |
id | pubmed-3254297 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32542972012-01-18 catena-Poly[1-[(2-fluorobenzylidene)amino]quinolinium [plumbate(II)-tri-μ-iodido]] Zhao, Hai-Rong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, {(C(16)H(12)FN(2))[PbI(3)]}(n), consists of 1-[(2-fluorobenzylidene)amino]quinolinium cations and a polymeric PbI(3) (−) anion formed by face-sharing PbI(6) octahedra. These octahedra form straight and regular infinite chains along the b axis. In the asymmetric unit, one cation and one anionic [PbI(3)](−) fragment are observed in general positions. Polymeric chains are produced by the glide plane perpendicular to the a axis. International Union of Crystallography 2011-12-07 /pmc/articles/PMC3254297/ /pubmed/22259325 http://dx.doi.org/10.1107/S1600536811051853 Text en © Hai-Rong Zhao 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhao, Hai-Rong catena-Poly[1-[(2-fluorobenzylidene)amino]quinolinium [plumbate(II)-tri-μ-iodido]] |
title |
catena-Poly[1-[(2-fluorobenzylidene)amino]quinolinium [plumbate(II)-tri-μ-iodido]] |
title_full |
catena-Poly[1-[(2-fluorobenzylidene)amino]quinolinium [plumbate(II)-tri-μ-iodido]] |
title_fullStr |
catena-Poly[1-[(2-fluorobenzylidene)amino]quinolinium [plumbate(II)-tri-μ-iodido]] |
title_full_unstemmed |
catena-Poly[1-[(2-fluorobenzylidene)amino]quinolinium [plumbate(II)-tri-μ-iodido]] |
title_short |
catena-Poly[1-[(2-fluorobenzylidene)amino]quinolinium [plumbate(II)-tri-μ-iodido]] |
title_sort | catena-poly[1-[(2-fluorobenzylidene)amino]quinolinium [plumbate(ii)-tri-μ-iodido]] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254297/ https://www.ncbi.nlm.nih.gov/pubmed/22259325 http://dx.doi.org/10.1107/S1600536811051853 |
work_keys_str_mv | AT zhaohairong catenapoly12fluorobenzylideneaminoquinoliniumplumbateiitrimiodido |