(12,17-Dieth­oxy­carbonyl-11,18-dimethyl-2,3:6,7-dibutano­corrphycenato)copper(II)–12,17-dieth­oxy­carbonyl-11,18-dimethyl-2:3,6:7-dibutano­corrphycene (3/97)

The corrphycene mol­ecule of the title compound, [Cu(C(36)H(36)N(4)O(4))](0.034).0.966C(36)H(38)N(4)O(4), has an essentially planar macrocyclic framwork with a slightly distorted trapezoidal N(4) core; the r.m.s. deviation of the peripheral 20 C atoms and four N atoms is 0.054 (3) Å. The surface are...

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Autores principales: Ohgo, Yoshiki, Yokoyama, Yuki, Hashizume, Daisuke, Neya, Saburo, Nakamura, Mikio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254300/
https://www.ncbi.nlm.nih.gov/pubmed/22259329
http://dx.doi.org/10.1107/S1600536811052214
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author Ohgo, Yoshiki
Yokoyama, Yuki
Hashizume, Daisuke
Neya, Saburo
Nakamura, Mikio
author_facet Ohgo, Yoshiki
Yokoyama, Yuki
Hashizume, Daisuke
Neya, Saburo
Nakamura, Mikio
author_sort Ohgo, Yoshiki
collection PubMed
description The corrphycene mol­ecule of the title compound, [Cu(C(36)H(36)N(4)O(4))](0.034).0.966C(36)H(38)N(4)O(4), has an essentially planar macrocyclic framwork with a slightly distorted trapezoidal N(4) core; the r.m.s. deviation of the peripheral 20 C atoms and four N atoms is 0.054 (3) Å. The surface area within the N(4)-coordinating core (8.358 Å(2)) is significantly smaller than that (8.503 Å(2)) of the corresponding free-base porphyrin. Two intra­molecular N—H⋯N hydrogen bonds are observed. Detailed structure analysis clarified that the co-crystallization of the free-base corrphycene together with a quite minor component (ca 3%) of corrphycenato–Cu(II) occurred in the recrystallization process.
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spelling pubmed-32543002012-01-18 (12,17-Dieth­oxy­carbonyl-11,18-dimethyl-2,3:6,7-dibutano­corrphycenato)copper(II)–12,17-dieth­oxy­carbonyl-11,18-dimethyl-2:3,6:7-dibutano­corrphycene (3/97) Ohgo, Yoshiki Yokoyama, Yuki Hashizume, Daisuke Neya, Saburo Nakamura, Mikio Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The corrphycene mol­ecule of the title compound, [Cu(C(36)H(36)N(4)O(4))](0.034).0.966C(36)H(38)N(4)O(4), has an essentially planar macrocyclic framwork with a slightly distorted trapezoidal N(4) core; the r.m.s. deviation of the peripheral 20 C atoms and four N atoms is 0.054 (3) Å. The surface area within the N(4)-coordinating core (8.358 Å(2)) is significantly smaller than that (8.503 Å(2)) of the corresponding free-base porphyrin. Two intra­molecular N—H⋯N hydrogen bonds are observed. Detailed structure analysis clarified that the co-crystallization of the free-base corrphycene together with a quite minor component (ca 3%) of corrphycenato–Cu(II) occurred in the recrystallization process. International Union of Crystallography 2011-12-10 /pmc/articles/PMC3254300/ /pubmed/22259329 http://dx.doi.org/10.1107/S1600536811052214 Text en © Ohgo et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ohgo, Yoshiki
Yokoyama, Yuki
Hashizume, Daisuke
Neya, Saburo
Nakamura, Mikio
(12,17-Dieth­oxy­carbonyl-11,18-dimethyl-2,3:6,7-dibutano­corrphycenato)copper(II)–12,17-dieth­oxy­carbonyl-11,18-dimethyl-2:3,6:7-dibutano­corrphycene (3/97)
title (12,17-Dieth­oxy­carbonyl-11,18-dimethyl-2,3:6,7-dibutano­corrphycenato)copper(II)–12,17-dieth­oxy­carbonyl-11,18-dimethyl-2:3,6:7-dibutano­corrphycene (3/97)
title_full (12,17-Dieth­oxy­carbonyl-11,18-dimethyl-2,3:6,7-dibutano­corrphycenato)copper(II)–12,17-dieth­oxy­carbonyl-11,18-dimethyl-2:3,6:7-dibutano­corrphycene (3/97)
title_fullStr (12,17-Dieth­oxy­carbonyl-11,18-dimethyl-2,3:6,7-dibutano­corrphycenato)copper(II)–12,17-dieth­oxy­carbonyl-11,18-dimethyl-2:3,6:7-dibutano­corrphycene (3/97)
title_full_unstemmed (12,17-Dieth­oxy­carbonyl-11,18-dimethyl-2,3:6,7-dibutano­corrphycenato)copper(II)–12,17-dieth­oxy­carbonyl-11,18-dimethyl-2:3,6:7-dibutano­corrphycene (3/97)
title_short (12,17-Dieth­oxy­carbonyl-11,18-dimethyl-2,3:6,7-dibutano­corrphycenato)copper(II)–12,17-dieth­oxy­carbonyl-11,18-dimethyl-2:3,6:7-dibutano­corrphycene (3/97)
title_sort (12,17-dieth­oxy­carbonyl-11,18-dimethyl-2,3:6,7-dibutano­corrphycenato)copper(ii)–12,17-dieth­oxy­carbonyl-11,18-dimethyl-2:3,6:7-dibutano­corrphycene (3/97)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254300/
https://www.ncbi.nlm.nih.gov/pubmed/22259329
http://dx.doi.org/10.1107/S1600536811052214
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