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trans-Tetraaquabis[bis(pyridin-3-yl)methanone-κN]manganese(II) bis(perchlorate)
In the title complex, [Mn(C(11)H(8)N(2)O)(2)(H(2)O)(4)](ClO(4))(2), the Mn(2+) ion is located on an inversion center with the slightly distorted N(2)O(4) octahedral coordination sphere comprising N-atom donors from two monodentate trans-related bis(pyridin-3-yl)methanone ligands and four water lig...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254301/ https://www.ncbi.nlm.nih.gov/pubmed/22259330 http://dx.doi.org/10.1107/S1600536811052184 |
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author | Liu, Bin Zhang, Fan |
author_facet | Liu, Bin Zhang, Fan |
author_sort | Liu, Bin |
collection | PubMed |
description | In the title complex, [Mn(C(11)H(8)N(2)O)(2)(H(2)O)(4)](ClO(4))(2), the Mn(2+) ion is located on an inversion center with the slightly distorted N(2)O(4) octahedral coordination sphere comprising N-atom donors from two monodentate trans-related bis(pyridin-3-yl)methanone ligands and four water ligands. The two perchlorate anions are linked to the mononuclear complex molecule through water O—H⋯O hydrogen bonds while inter-complex water O—H⋯N(pyridine) interactions form an infinite chain structure extending along the b axis. The perchlorate anions also function as inter-unit links through water O—H⋯O hydrogen bonds which, together with water O—H⋯O(carbonyl) interactions, give a three-dimensional framework structure. |
format | Online Article Text |
id | pubmed-3254301 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32543012012-01-18 trans-Tetraaquabis[bis(pyridin-3-yl)methanone-κN]manganese(II) bis(perchlorate) Liu, Bin Zhang, Fan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(11)H(8)N(2)O)(2)(H(2)O)(4)](ClO(4))(2), the Mn(2+) ion is located on an inversion center with the slightly distorted N(2)O(4) octahedral coordination sphere comprising N-atom donors from two monodentate trans-related bis(pyridin-3-yl)methanone ligands and four water ligands. The two perchlorate anions are linked to the mononuclear complex molecule through water O—H⋯O hydrogen bonds while inter-complex water O—H⋯N(pyridine) interactions form an infinite chain structure extending along the b axis. The perchlorate anions also function as inter-unit links through water O—H⋯O hydrogen bonds which, together with water O—H⋯O(carbonyl) interactions, give a three-dimensional framework structure. International Union of Crystallography 2011-12-10 /pmc/articles/PMC3254301/ /pubmed/22259330 http://dx.doi.org/10.1107/S1600536811052184 Text en © Liu and Zhang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Bin Zhang, Fan trans-Tetraaquabis[bis(pyridin-3-yl)methanone-κN]manganese(II) bis(perchlorate) |
title |
trans-Tetraaquabis[bis(pyridin-3-yl)methanone-κN]manganese(II) bis(perchlorate) |
title_full |
trans-Tetraaquabis[bis(pyridin-3-yl)methanone-κN]manganese(II) bis(perchlorate) |
title_fullStr |
trans-Tetraaquabis[bis(pyridin-3-yl)methanone-κN]manganese(II) bis(perchlorate) |
title_full_unstemmed |
trans-Tetraaquabis[bis(pyridin-3-yl)methanone-κN]manganese(II) bis(perchlorate) |
title_short |
trans-Tetraaquabis[bis(pyridin-3-yl)methanone-κN]manganese(II) bis(perchlorate) |
title_sort | trans-tetraaquabis[bis(pyridin-3-yl)methanone-κn]manganese(ii) bis(perchlorate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254301/ https://www.ncbi.nlm.nih.gov/pubmed/22259330 http://dx.doi.org/10.1107/S1600536811052184 |
work_keys_str_mv | AT liubin transtetraaquabisbispyridin3ylmethanoneknmanganeseiibisperchlorate AT zhangfan transtetraaquabisbispyridin3ylmethanoneknmanganeseiibisperchlorate |