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trans-Tetra­aqua­bis­[bis­(pyridin-3-yl)methanone-κN]manganese(II) bis­(perchlorate)

In the title complex, [Mn(C(11)H(8)N(2)O)(2)(H(2)O)(4)](ClO(4))(2), the Mn(2+) ion is located on an inversion center with the slightly distorted N(2)O(4) octa­hedral coordination sphere comprising N-atom donors from two monodentate trans-related bis­(pyridin-3-yl)methanone ligands and four water lig...

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Detalles Bibliográficos
Autores principales: Liu, Bin, Zhang, Fan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254301/
https://www.ncbi.nlm.nih.gov/pubmed/22259330
http://dx.doi.org/10.1107/S1600536811052184
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author Liu, Bin
Zhang, Fan
author_facet Liu, Bin
Zhang, Fan
author_sort Liu, Bin
collection PubMed
description In the title complex, [Mn(C(11)H(8)N(2)O)(2)(H(2)O)(4)](ClO(4))(2), the Mn(2+) ion is located on an inversion center with the slightly distorted N(2)O(4) octa­hedral coordination sphere comprising N-atom donors from two monodentate trans-related bis­(pyridin-3-yl)methanone ligands and four water ligands. The two perchlorate anions are linked to the mononuclear complex mol­ecule through water O—H⋯O hydrogen bonds while inter-complex water O—H⋯N(pyridine) inter­actions form an infinite chain structure extending along the b axis. The perchlorate anions also function as inter-unit links through water O—H⋯O hydrogen bonds which, together with water O—H⋯O(carbon­yl) inter­actions, give a three-dimensional framework structure.
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spelling pubmed-32543012012-01-18 trans-Tetra­aqua­bis­[bis­(pyridin-3-yl)methanone-κN]manganese(II) bis­(perchlorate) Liu, Bin Zhang, Fan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(11)H(8)N(2)O)(2)(H(2)O)(4)](ClO(4))(2), the Mn(2+) ion is located on an inversion center with the slightly distorted N(2)O(4) octa­hedral coordination sphere comprising N-atom donors from two monodentate trans-related bis­(pyridin-3-yl)methanone ligands and four water ligands. The two perchlorate anions are linked to the mononuclear complex mol­ecule through water O—H⋯O hydrogen bonds while inter-complex water O—H⋯N(pyridine) inter­actions form an infinite chain structure extending along the b axis. The perchlorate anions also function as inter-unit links through water O—H⋯O hydrogen bonds which, together with water O—H⋯O(carbon­yl) inter­actions, give a three-dimensional framework structure. International Union of Crystallography 2011-12-10 /pmc/articles/PMC3254301/ /pubmed/22259330 http://dx.doi.org/10.1107/S1600536811052184 Text en © Liu and Zhang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Bin
Zhang, Fan
trans-Tetra­aqua­bis­[bis­(pyridin-3-yl)methanone-κN]manganese(II) bis­(perchlorate)
title trans-Tetra­aqua­bis­[bis­(pyridin-3-yl)methanone-κN]manganese(II) bis­(perchlorate)
title_full trans-Tetra­aqua­bis­[bis­(pyridin-3-yl)methanone-κN]manganese(II) bis­(perchlorate)
title_fullStr trans-Tetra­aqua­bis­[bis­(pyridin-3-yl)methanone-κN]manganese(II) bis­(perchlorate)
title_full_unstemmed trans-Tetra­aqua­bis­[bis­(pyridin-3-yl)methanone-κN]manganese(II) bis­(perchlorate)
title_short trans-Tetra­aqua­bis­[bis­(pyridin-3-yl)methanone-κN]manganese(II) bis­(perchlorate)
title_sort trans-tetra­aqua­bis­[bis­(pyridin-3-yl)methanone-κn]manganese(ii) bis­(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254301/
https://www.ncbi.nlm.nih.gov/pubmed/22259330
http://dx.doi.org/10.1107/S1600536811052184
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