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Di-μ-oxido-bis­[(2-eth­oxy-6-{[2-(2-hy­droxy­ethyl­amino)­ethyl­imino]­meth­yl}phenolato-κ(3) N,N′,O (1))oxidovanadium(V)]

In the title centrosymmetric dinuclear dioxidovanadium(V) complex, [V(2)(C(13)H(19)N(2)O(3))(2)O(4)], the V(V) ion is coordinated by an N,N′,O-tridendate 2-eth­oxy-6-{[2-(2-hy­droxy­ethyl­amino)­ethyl­imino]­meth­yl}phenolate ligand and three oxide O atoms, forming a distorted cis-VN(2)O(4) octa­hed...

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Detalles Bibliográficos
Autor principal: Wang, Fu-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254302/
https://www.ncbi.nlm.nih.gov/pubmed/22259331
http://dx.doi.org/10.1107/S160053681105094X
Descripción
Sumario:In the title centrosymmetric dinuclear dioxidovanadium(V) complex, [V(2)(C(13)H(19)N(2)O(3))(2)O(4)], the V(V) ion is coordinated by an N,N′,O-tridendate 2-eth­oxy-6-{[2-(2-hy­droxy­ethyl­amino)­ethyl­imino]­meth­yl}phenolate ligand and three oxide O atoms, forming a distorted cis-VN(2)O(4) octa­hedral geometry. The bridging O atoms show one short and one long bond to their two attached V(V) atoms. The dihedral angle between the benzene ring of the ligand and the V(2)O(2) plane is 75.2 (3)°. The deviation of the V(V) ion from the plane defined by the three donor atoms of the tridentate ligand and one bridging oxide O atom is 0.337 (2) Å towards the terminal oxide O atom. Two N—H⋯O hydrogen bonds help to establish the conformation of the dimer. In the crystal, the complex mol­ecules are linked by O—H⋯O hydrogen bonds, forming [100] chains.