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Di-μ-oxido-bis[(2-ethoxy-6-{[2-(2-hydroxyethylamino)ethylimino]methyl}phenolato-κ(3) N,N′,O (1))oxidovanadium(V)]
In the title centrosymmetric dinuclear dioxidovanadium(V) complex, [V(2)(C(13)H(19)N(2)O(3))(2)O(4)], the V(V) ion is coordinated by an N,N′,O-tridendate 2-ethoxy-6-{[2-(2-hydroxyethylamino)ethylimino]methyl}phenolate ligand and three oxide O atoms, forming a distorted cis-VN(2)O(4) octahed...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254302/ https://www.ncbi.nlm.nih.gov/pubmed/22259331 http://dx.doi.org/10.1107/S160053681105094X |
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author | Wang, Fu-Ming |
author_facet | Wang, Fu-Ming |
author_sort | Wang, Fu-Ming |
collection | PubMed |
description | In the title centrosymmetric dinuclear dioxidovanadium(V) complex, [V(2)(C(13)H(19)N(2)O(3))(2)O(4)], the V(V) ion is coordinated by an N,N′,O-tridendate 2-ethoxy-6-{[2-(2-hydroxyethylamino)ethylimino]methyl}phenolate ligand and three oxide O atoms, forming a distorted cis-VN(2)O(4) octahedral geometry. The bridging O atoms show one short and one long bond to their two attached V(V) atoms. The dihedral angle between the benzene ring of the ligand and the V(2)O(2) plane is 75.2 (3)°. The deviation of the V(V) ion from the plane defined by the three donor atoms of the tridentate ligand and one bridging oxide O atom is 0.337 (2) Å towards the terminal oxide O atom. Two N—H⋯O hydrogen bonds help to establish the conformation of the dimer. In the crystal, the complex molecules are linked by O—H⋯O hydrogen bonds, forming [100] chains. |
format | Online Article Text |
id | pubmed-3254302 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32543022012-01-18 Di-μ-oxido-bis[(2-ethoxy-6-{[2-(2-hydroxyethylamino)ethylimino]methyl}phenolato-κ(3) N,N′,O (1))oxidovanadium(V)] Wang, Fu-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric dinuclear dioxidovanadium(V) complex, [V(2)(C(13)H(19)N(2)O(3))(2)O(4)], the V(V) ion is coordinated by an N,N′,O-tridendate 2-ethoxy-6-{[2-(2-hydroxyethylamino)ethylimino]methyl}phenolate ligand and three oxide O atoms, forming a distorted cis-VN(2)O(4) octahedral geometry. The bridging O atoms show one short and one long bond to their two attached V(V) atoms. The dihedral angle between the benzene ring of the ligand and the V(2)O(2) plane is 75.2 (3)°. The deviation of the V(V) ion from the plane defined by the three donor atoms of the tridentate ligand and one bridging oxide O atom is 0.337 (2) Å towards the terminal oxide O atom. Two N—H⋯O hydrogen bonds help to establish the conformation of the dimer. In the crystal, the complex molecules are linked by O—H⋯O hydrogen bonds, forming [100] chains. International Union of Crystallography 2011-12-10 /pmc/articles/PMC3254302/ /pubmed/22259331 http://dx.doi.org/10.1107/S160053681105094X Text en © Fu-Ming Wang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Fu-Ming Di-μ-oxido-bis[(2-ethoxy-6-{[2-(2-hydroxyethylamino)ethylimino]methyl}phenolato-κ(3) N,N′,O (1))oxidovanadium(V)] |
title | Di-μ-oxido-bis[(2-ethoxy-6-{[2-(2-hydroxyethylamino)ethylimino]methyl}phenolato-κ(3)
N,N′,O
(1))oxidovanadium(V)] |
title_full | Di-μ-oxido-bis[(2-ethoxy-6-{[2-(2-hydroxyethylamino)ethylimino]methyl}phenolato-κ(3)
N,N′,O
(1))oxidovanadium(V)] |
title_fullStr | Di-μ-oxido-bis[(2-ethoxy-6-{[2-(2-hydroxyethylamino)ethylimino]methyl}phenolato-κ(3)
N,N′,O
(1))oxidovanadium(V)] |
title_full_unstemmed | Di-μ-oxido-bis[(2-ethoxy-6-{[2-(2-hydroxyethylamino)ethylimino]methyl}phenolato-κ(3)
N,N′,O
(1))oxidovanadium(V)] |
title_short | Di-μ-oxido-bis[(2-ethoxy-6-{[2-(2-hydroxyethylamino)ethylimino]methyl}phenolato-κ(3)
N,N′,O
(1))oxidovanadium(V)] |
title_sort | di-μ-oxido-bis[(2-ethoxy-6-{[2-(2-hydroxyethylamino)ethylimino]methyl}phenolato-κ(3)
n,n′,o
(1))oxidovanadium(v)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254302/ https://www.ncbi.nlm.nih.gov/pubmed/22259331 http://dx.doi.org/10.1107/S160053681105094X |
work_keys_str_mv | AT wangfuming dimoxidobis2ethoxy622hydroxyethylaminoethyliminomethylphenolatok3nno1oxidovanadiumv |