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Aquabis(1,1,1,5,5,5-hexafluoroacetylacetonato)[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine]ytterbium(III) chloride methanol monosolvate monohydrate
The title compound, [Yb(C(5)HF(6)O(2))(2)(C(20)H(14)N(4))(H(2)O)]Cl·CH(3)OH·H(2)O, adopts an eight-coordinated geometry around the Yb(III) atom consisting of a 4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine (pytpy) ligand, two 1,1,1,5,5,5-hexafluoroacetylacetonate (hfac) anions and an aqua ligand. In th...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254304/ https://www.ncbi.nlm.nih.gov/pubmed/22259333 http://dx.doi.org/10.1107/S1600536811052378 |
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author | Okawara, Toru Feng, Jiang Abe, Masaaki Hisaeda, Yoshio |
author_facet | Okawara, Toru Feng, Jiang Abe, Masaaki Hisaeda, Yoshio |
author_sort | Okawara, Toru |
collection | PubMed |
description | The title compound, [Yb(C(5)HF(6)O(2))(2)(C(20)H(14)N(4))(H(2)O)]Cl·CH(3)OH·H(2)O, adopts an eight-coordinated geometry around the Yb(III) atom consisting of a 4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine (pytpy) ligand, two 1,1,1,5,5,5-hexafluoroacetylacetonate (hfac) anions and an aqua ligand. In the solid state, the compound forms supramolecular chains running along the b-axis via intermolecular hydrogen bonds between the Yb—OH(2) unit and the N-atom donor of the 4-pyridyl pendant of pytpy, with an O⋯N distance of 2.686 (4) Å. A chloride counter-anion and lattice methanol and water solvent molecules occupy a hydrophilic columnar space along the coordination chains. O—H⋯Cl hydrogen bonds occur. The two water molecules and the four trifluoromethyl groups are disordered over two sets of sites, each with different occupancy ratios. |
format | Online Article Text |
id | pubmed-3254304 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32543042012-01-18 Aquabis(1,1,1,5,5,5-hexafluoroacetylacetonato)[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine]ytterbium(III) chloride methanol monosolvate monohydrate Okawara, Toru Feng, Jiang Abe, Masaaki Hisaeda, Yoshio Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Yb(C(5)HF(6)O(2))(2)(C(20)H(14)N(4))(H(2)O)]Cl·CH(3)OH·H(2)O, adopts an eight-coordinated geometry around the Yb(III) atom consisting of a 4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine (pytpy) ligand, two 1,1,1,5,5,5-hexafluoroacetylacetonate (hfac) anions and an aqua ligand. In the solid state, the compound forms supramolecular chains running along the b-axis via intermolecular hydrogen bonds between the Yb—OH(2) unit and the N-atom donor of the 4-pyridyl pendant of pytpy, with an O⋯N distance of 2.686 (4) Å. A chloride counter-anion and lattice methanol and water solvent molecules occupy a hydrophilic columnar space along the coordination chains. O—H⋯Cl hydrogen bonds occur. The two water molecules and the four trifluoromethyl groups are disordered over two sets of sites, each with different occupancy ratios. International Union of Crystallography 2011-12-10 /pmc/articles/PMC3254304/ /pubmed/22259333 http://dx.doi.org/10.1107/S1600536811052378 Text en © Okawara et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Okawara, Toru Feng, Jiang Abe, Masaaki Hisaeda, Yoshio Aquabis(1,1,1,5,5,5-hexafluoroacetylacetonato)[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine]ytterbium(III) chloride methanol monosolvate monohydrate |
title | Aquabis(1,1,1,5,5,5-hexafluoroacetylacetonato)[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine]ytterbium(III) chloride methanol monosolvate monohydrate |
title_full | Aquabis(1,1,1,5,5,5-hexafluoroacetylacetonato)[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine]ytterbium(III) chloride methanol monosolvate monohydrate |
title_fullStr | Aquabis(1,1,1,5,5,5-hexafluoroacetylacetonato)[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine]ytterbium(III) chloride methanol monosolvate monohydrate |
title_full_unstemmed | Aquabis(1,1,1,5,5,5-hexafluoroacetylacetonato)[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine]ytterbium(III) chloride methanol monosolvate monohydrate |
title_short | Aquabis(1,1,1,5,5,5-hexafluoroacetylacetonato)[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine]ytterbium(III) chloride methanol monosolvate monohydrate |
title_sort | aquabis(1,1,1,5,5,5-hexafluoroacetylacetonato)[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine]ytterbium(iii) chloride methanol monosolvate monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254304/ https://www.ncbi.nlm.nih.gov/pubmed/22259333 http://dx.doi.org/10.1107/S1600536811052378 |
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