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2,9-Dimethyl-1,10-phenanthrolin-1-ium (6-carb­oxy-4-hy­droxy­pyridine-2-carboxyl­ato-κ(3) O (2),N,O (6))(4-hy­droxy­pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))zincate(II) 2.35-hydrate: a proton-transfer compound

In the title compound, (C(14)H(13)N(2))[Zn(C(7)H(3)NO(5))(C(7)H(4)NO(5))]·2.35H(2)O, the Zn(II) atom is coordinated by two N atoms and four O atoms from the carboxyl­ate groups of the 4-hy­droxy­pyridine-2,6-dicarboxyl­ate and 6-carb­oxy-4-hy­droxy­pyridine-2-carboxyl­ate ligands, forming a distored...

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Detalles Bibliográficos
Autores principales: Derikvand, Zohreh, Stoeckli-Evans, Helen, Nemati, Andya
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254305/
https://www.ncbi.nlm.nih.gov/pubmed/22259335
http://dx.doi.org/10.1107/S1600536811052445
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author Derikvand, Zohreh
Stoeckli-Evans, Helen
Nemati, Andya
author_facet Derikvand, Zohreh
Stoeckli-Evans, Helen
Nemati, Andya
author_sort Derikvand, Zohreh
collection PubMed
description In the title compound, (C(14)H(13)N(2))[Zn(C(7)H(3)NO(5))(C(7)H(4)NO(5))]·2.35H(2)O, the Zn(II) atom is coordinated by two N atoms and four O atoms from the carboxyl­ate groups of the 4-hy­droxy­pyridine-2,6-dicarboxyl­ate and 6-carb­oxy-4-hy­droxy­pyridine-2-carboxyl­ate ligands, forming a distored octa­hedral geometry. In the anion, the two pyridine rings are inclined to one another by 87.75 (13)°. Two types of robust O—H⋯O hydrogen bond synthons, viz. R (2) (2)(16) and R (6) (6)(42), link the anions to form a two-dimensional network parallel to the bc plane. Furthermore, O—H⋯O, N—H⋯O, N—H⋯N and weak C—H⋯O hydrogen bonds connect the two dimensional networks, forming a three-dimensional structure. In the crystal, there are also C—H⋯π and π–π inter­actions [centroid–centroid distances of 3.5554 (18) and 3.7681 (18) Å], and C=O⋯π inter­actions [O⋯centroid distance = 3.117 (2) Å] present. One of the three crystal water molecules shows an occupancy of 0.35.
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spelling pubmed-32543052012-01-18 2,9-Dimethyl-1,10-phenanthrolin-1-ium (6-carb­oxy-4-hy­droxy­pyridine-2-carboxyl­ato-κ(3) O (2),N,O (6))(4-hy­droxy­pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))zincate(II) 2.35-hydrate: a proton-transfer compound Derikvand, Zohreh Stoeckli-Evans, Helen Nemati, Andya Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(14)H(13)N(2))[Zn(C(7)H(3)NO(5))(C(7)H(4)NO(5))]·2.35H(2)O, the Zn(II) atom is coordinated by two N atoms and four O atoms from the carboxyl­ate groups of the 4-hy­droxy­pyridine-2,6-dicarboxyl­ate and 6-carb­oxy-4-hy­droxy­pyridine-2-carboxyl­ate ligands, forming a distored octa­hedral geometry. In the anion, the two pyridine rings are inclined to one another by 87.75 (13)°. Two types of robust O—H⋯O hydrogen bond synthons, viz. R (2) (2)(16) and R (6) (6)(42), link the anions to form a two-dimensional network parallel to the bc plane. Furthermore, O—H⋯O, N—H⋯O, N—H⋯N and weak C—H⋯O hydrogen bonds connect the two dimensional networks, forming a three-dimensional structure. In the crystal, there are also C—H⋯π and π–π inter­actions [centroid–centroid distances of 3.5554 (18) and 3.7681 (18) Å], and C=O⋯π inter­actions [O⋯centroid distance = 3.117 (2) Å] present. One of the three crystal water molecules shows an occupancy of 0.35. International Union of Crystallography 2011-12-10 /pmc/articles/PMC3254305/ /pubmed/22259335 http://dx.doi.org/10.1107/S1600536811052445 Text en © Derikvand et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Derikvand, Zohreh
Stoeckli-Evans, Helen
Nemati, Andya
2,9-Dimethyl-1,10-phenanthrolin-1-ium (6-carb­oxy-4-hy­droxy­pyridine-2-carboxyl­ato-κ(3) O (2),N,O (6))(4-hy­droxy­pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))zincate(II) 2.35-hydrate: a proton-transfer compound
title 2,9-Dimethyl-1,10-phenanthrolin-1-ium (6-carb­oxy-4-hy­droxy­pyridine-2-carboxyl­ato-κ(3) O (2),N,O (6))(4-hy­droxy­pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))zincate(II) 2.35-hydrate: a proton-transfer compound
title_full 2,9-Dimethyl-1,10-phenanthrolin-1-ium (6-carb­oxy-4-hy­droxy­pyridine-2-carboxyl­ato-κ(3) O (2),N,O (6))(4-hy­droxy­pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))zincate(II) 2.35-hydrate: a proton-transfer compound
title_fullStr 2,9-Dimethyl-1,10-phenanthrolin-1-ium (6-carb­oxy-4-hy­droxy­pyridine-2-carboxyl­ato-κ(3) O (2),N,O (6))(4-hy­droxy­pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))zincate(II) 2.35-hydrate: a proton-transfer compound
title_full_unstemmed 2,9-Dimethyl-1,10-phenanthrolin-1-ium (6-carb­oxy-4-hy­droxy­pyridine-2-carboxyl­ato-κ(3) O (2),N,O (6))(4-hy­droxy­pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))zincate(II) 2.35-hydrate: a proton-transfer compound
title_short 2,9-Dimethyl-1,10-phenanthrolin-1-ium (6-carb­oxy-4-hy­droxy­pyridine-2-carboxyl­ato-κ(3) O (2),N,O (6))(4-hy­droxy­pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))zincate(II) 2.35-hydrate: a proton-transfer compound
title_sort 2,9-dimethyl-1,10-phenanthrolin-1-ium (6-carb­oxy-4-hy­droxy­pyridine-2-carboxyl­ato-κ(3) o (2),n,o (6))(4-hy­droxy­pyridine-2,6-dicarboxyl­ato-κ(3) o (2),n,o (6))zincate(ii) 2.35-hydrate: a proton-transfer compound
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254305/
https://www.ncbi.nlm.nih.gov/pubmed/22259335
http://dx.doi.org/10.1107/S1600536811052445
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AT stoecklievanshelen 29dimethyl110phenanthrolin1ium6carboxy4hydroxypyridine2carboxylatok3o2no64hydroxypyridine26dicarboxylatok3o2no6zincateii235hydrateaprotontransfercompound
AT nematiandya 29dimethyl110phenanthrolin1ium6carboxy4hydroxypyridine2carboxylatok3o2no64hydroxypyridine26dicarboxylatok3o2no6zincateii235hydrateaprotontransfercompound