Bis(tetra­phenyl­phospho­nium) bis­[N-(trifluoro­methyl­sulfon­yl)dithio­carbimato(2−)-κ(2) S,S′]zincate(II)

The title salt, (C(24)H(20)P)(2)[Zn(C(2)F(3)NO(2)S(3))(2)], consists of a complex dianion and two tetra­phenyl­phospho­nium cations. The Zn(II) ion displays a distorted tetra­hedral coordination environment with four S atoms from two S,S′-chelated N-(trifluoro­methyl­sulfonyl­)dithio­carbimate anion...

Descripción completa

Detalles Bibliográficos
Autores principales: Pinto, Paula S., Rubinger, Mayura M. M., Guilardi, Silvana, Paixão, Drielly A., Oliveira, Marcelo R. L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254306/
https://www.ncbi.nlm.nih.gov/pubmed/22259336
http://dx.doi.org/10.1107/S160053681105207X
Descripción
Sumario:The title salt, (C(24)H(20)P)(2)[Zn(C(2)F(3)NO(2)S(3))(2)], consists of a complex dianion and two tetra­phenyl­phospho­nium cations. The Zn(II) ion displays a distorted tetra­hedral coordination environment with four S atoms from two S,S′-chelated N-(trifluoro­methyl­sulfonyl­)dithio­carbimate anions. In the crystal, besides the ionic inter­action of the oppositely charged ions, inter­molecular C—H⋯O inter­actions between cations and anions are observed. One of the cations inter­acts with an inversion-related equivalent by π–π stacking between phenyl rings, with a centroid–centroid distance of 3.932 (4) Å.

Ejemplares similares