Bis(tetra­phenyl­phospho­nium) bis­[N-(trifluoro­methyl­sulfon­yl)dithio­carbimato(2−)-κ(2) S,S′]zincate(II)

The title salt, (C(24)H(20)P)(2)[Zn(C(2)F(3)NO(2)S(3))(2)], consists of a complex dianion and two tetra­phenyl­phospho­nium cations. The Zn(II) ion displays a distorted tetra­hedral coordination environment with four S atoms from two S,S′-chelated N-(trifluoro­methyl­sulfonyl­)dithio­carbimate anion...

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Detalles Bibliográficos
Autores principales: Pinto, Paula S., Rubinger, Mayura M. M., Guilardi, Silvana, Paixão, Drielly A., Oliveira, Marcelo R. L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254306/
https://www.ncbi.nlm.nih.gov/pubmed/22259336
http://dx.doi.org/10.1107/S160053681105207X
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author Pinto, Paula S.
Rubinger, Mayura M. M.
Guilardi, Silvana
Paixão, Drielly A.
Oliveira, Marcelo R. L.
author_facet Pinto, Paula S.
Rubinger, Mayura M. M.
Guilardi, Silvana
Paixão, Drielly A.
Oliveira, Marcelo R. L.
author_sort Pinto, Paula S.
collection PubMed
description The title salt, (C(24)H(20)P)(2)[Zn(C(2)F(3)NO(2)S(3))(2)], consists of a complex dianion and two tetra­phenyl­phospho­nium cations. The Zn(II) ion displays a distorted tetra­hedral coordination environment with four S atoms from two S,S′-chelated N-(trifluoro­methyl­sulfonyl­)dithio­carbimate anions. In the crystal, besides the ionic inter­action of the oppositely charged ions, inter­molecular C—H⋯O inter­actions between cations and anions are observed. One of the cations inter­acts with an inversion-related equivalent by π–π stacking between phenyl rings, with a centroid–centroid distance of 3.932 (4) Å.
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spelling pubmed-32543062012-01-18 Bis(tetra­phenyl­phospho­nium) bis­[N-(trifluoro­methyl­sulfon­yl)dithio­carbimato(2−)-κ(2) S,S′]zincate(II) Pinto, Paula S. Rubinger, Mayura M. M. Guilardi, Silvana Paixão, Drielly A. Oliveira, Marcelo R. L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title salt, (C(24)H(20)P)(2)[Zn(C(2)F(3)NO(2)S(3))(2)], consists of a complex dianion and two tetra­phenyl­phospho­nium cations. The Zn(II) ion displays a distorted tetra­hedral coordination environment with four S atoms from two S,S′-chelated N-(trifluoro­methyl­sulfonyl­)dithio­carbimate anions. In the crystal, besides the ionic inter­action of the oppositely charged ions, inter­molecular C—H⋯O inter­actions between cations and anions are observed. One of the cations inter­acts with an inversion-related equivalent by π–π stacking between phenyl rings, with a centroid–centroid distance of 3.932 (4) Å. International Union of Crystallography 2011-12-10 /pmc/articles/PMC3254306/ /pubmed/22259336 http://dx.doi.org/10.1107/S160053681105207X Text en © Pinto et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Pinto, Paula S.
Rubinger, Mayura M. M.
Guilardi, Silvana
Paixão, Drielly A.
Oliveira, Marcelo R. L.
Bis(tetra­phenyl­phospho­nium) bis­[N-(trifluoro­methyl­sulfon­yl)dithio­carbimato(2−)-κ(2) S,S′]zincate(II)
title Bis(tetra­phenyl­phospho­nium) bis­[N-(trifluoro­methyl­sulfon­yl)dithio­carbimato(2−)-κ(2) S,S′]zincate(II)
title_full Bis(tetra­phenyl­phospho­nium) bis­[N-(trifluoro­methyl­sulfon­yl)dithio­carbimato(2−)-κ(2) S,S′]zincate(II)
title_fullStr Bis(tetra­phenyl­phospho­nium) bis­[N-(trifluoro­methyl­sulfon­yl)dithio­carbimato(2−)-κ(2) S,S′]zincate(II)
title_full_unstemmed Bis(tetra­phenyl­phospho­nium) bis­[N-(trifluoro­methyl­sulfon­yl)dithio­carbimato(2−)-κ(2) S,S′]zincate(II)
title_short Bis(tetra­phenyl­phospho­nium) bis­[N-(trifluoro­methyl­sulfon­yl)dithio­carbimato(2−)-κ(2) S,S′]zincate(II)
title_sort bis(tetra­phenyl­phospho­nium) bis­[n-(trifluoro­methyl­sulfon­yl)dithio­carbimato(2−)-κ(2) s,s′]zincate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3254306/
https://www.ncbi.nlm.nih.gov/pubmed/22259336
http://dx.doi.org/10.1107/S160053681105207X
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